Introducing the Azlactone Functionality into Polymers through Controlled Radical Polymerization: Strategies and Recent Developments

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doi:10.1071/CH12192

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Introducing the Azlactone Functionality into Polymers through Controlled Radical Polymerization: Strategies and Recent Developments

H. T. Ho ^A, M. E. Levere ^A, D. Fournier ^A ^B, V. Montembault ^A, S. Pascual ^A and L. Fontaine ^A ^C

^A Equipe Méthodologie et Synthèse des Polymères, Institut des Molécules et des Matériaux du Mans, IMMM UMR CNRS 6283, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.
^B Present address: Unité des Matériaux Et Transformations (UMET, UMR CNRS 8207) Ingénierie des Systèmes Polymères Team, Université Lille 1, 59655 Villeneuve d’Ascq Cedex, France.
^C Corresponding author. Email: laurent.fontaine@univ-lemans.fr

Australian Journal of Chemistry 65(8) 970-977 http://dx.doi.org/10.1071/CH12192
Submitted: 11 April 2012 Accepted: 15 May 2012 Published: 2 August 2012





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Abstract

Polymers containing the highly reactive azlactone group have emerged as a powerful platform useful in various application areas. This Highlight summarizes recent developments in the field of azlactone-derived polymers made in our group using controlled radical polymerizations (ATRP and RAFT) and ‘click’ chemistry methodology (thiol-Michael addition), leading to well defined reactive polymers.

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