|
Synthesis of Symmetrical, Substituted (alkane-α,ω-diyl)(bis[3,3′-allyl dithioethers]) Monomers for Photoplastic Polymer Networks
Cornelis M.
Moorhoff A,
Wayne D.
Cook A C,
Tara
Schiller A,
Carl
Braybrook B and
San H.
Thang A B
A
Department of Materials Engineering, Monash University, Clayton, Vic. 3800, Australia.
B
Materials Science and Engineering, CSIRO, Clayton, Vic. 3168, Australia.
C
Corresponding author. Email: wayne.cook@monash.edu
Australian Journal of Chemistry
65(8)
1165-1176 http://dx.doi.org/10.1071/CH12278
Submitted: 12 June 2012 Accepted: 20 July 2012 Published:
8
August
2012
|  |
|
|
Abstract
Novel symmetrical (alkane-α,ω-diyl)(bis[3,3′-allyl dithioethers]) compounds and their ether analogues, have been synthesised from (alkane-α,ω-diyl)bis([2-{chloromethyl}allyl]sulfane) precursors, for use in crosslinked polymers which exhibit photoplastic behaviour. Facile synthesis and purification of these monomers was achieved if the alkane-α,ω-diyl moiety had at least one oxygen atom in this linker. The number of sulfur atoms in these monomers was varied from four to two to zero to produce monomers which can be used to evaluate their importance on the photoplasticity behaviour. 
|
References
[1]
C. M. Moorhoff, W. D. Cook, F. Chen, D. Nghiem, C. Braybrook, S. Thang, J. Sun, T. F. Scott, C. N. Bowman, Aust. J. Chem. 2011, 64, 1083.
| CrossRef | CAS | 
[2]
W. D. Cook, F. Chen, Q. D. Nghiem, T. F. Scott, C. N. Bowman, S. Chausson, L. Le Pluart, Macromol. Symp. 2010, 291, 50.
| CrossRef |
[3]
W. D. Cook, S. Chausson, F. Chen, L. Le Pluart, C. N. Bowman, T. F. Scott, Polym. Int. 2008, 57, 469.
| CrossRef | CAS |
[4]
T. F. Scott, A. D. Schneider, W. D. Cook, C. N. Bowman, Science 2005, 308, 1615.
| CrossRef | CAS |
[5]
W. D. Cook, M. Forrest, A. A. Goodwin, Dent. Mat. 1999, 15, 447.
| CrossRef | CAS |
[6]
R. E. Evans, E. Rizzardo, Macromolecules 2000, 33, 6722.
| CrossRef | CAS |
[7]
R. E. Evans, E. Rizzardo, J. Polym. Sci. Pol. Chem. 2001, 39, 202.
| CrossRef | CAS |
[8]
T. F. Scott, R. B. Draughon, C. N. Bowman, Adv. Mater. 2006, 18, 2128.
| CrossRef | CAS |
[9]
C. J. Kloxin, T. F. Scott, C. N. Bowman, Macromolecules 2009, 42, 2551.
| CrossRef | CAS |
[10]
L. Pauling, The Nature of the Chemical Bond 1960, 3rd edn (Cornell University: New York, NY).
[11]
L. C. Allen, J. Am. Chem. Soc. 1989, 111, 9003.
| CrossRef | CAS |
[12]
K. Nishide, S.-i. Ohsugi, T. Miyamoto, K. Kumar, M. Node, Monatsh. Chem. 2004, 135, 189.
| CrossRef | CAS |
[13]
G. Socrates, Infrared and Raman Characteristic Group Frequencies: Tables and Charts 2008, 3rd edn (John Wiley and Sons: Sussex).
|
|
 |
Subscriber Login |
 |
|
e-Alerts
Connect with us
