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Facile Fabrication of Au–F127 Nanocolloids with Different Morphologies and their Potential Bioapplications
Qinshu
Zhu A E,
Chong
Sun A B E,
Jie
Yan A,
Kai
Yang A,
Rongjin
Fu C,
Chun
Mao A D and
Jian
Shen A D
A
Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China.
B
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
C
Nanjing Institute of Supervision & Testing on Product Quality, Nanjing 210028, China.
D
Corresponding authors. Email: maochun127@yahoo.cn; jshen@njnu.edu.cn
E
These authors contributed equally to this work.
Australian Journal of Chemistry
66(3)
381-390 http://dx.doi.org/10.1071/CH12482
Submitted: 22 October 2012 Accepted: 4 December 2012 Published:
23
January
2013
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Abstract
Three kinds of novel facile fabrication routes to prepare Au–F127 nanocolloids with different morphologies including rambutan-like Au–F127 hybrid nanospheres, Au@F127 core–shell nanostructure, and multiple shapes of Au nanosheets are reported. The different Au–F127 nanocolloids are characterised by transmission electron microscopy, electron diffraction patterns, and UV-vis spectroscopy. The different formation mechanisms of the Au–F127 nanocolloids with different morphologies are discussed. The intrinsic properties and application potential of Au–F127 nanocolloids are determined by their size, shape, composition, and structure. A biosensor made of rambutan-like Au–F127 hybrid nanospheres exhibited a good electrocatalytic activity for the reduction of hydrogen peroxide. The Au@F127 core–shell nanoparticles exhibited good blood compatibility attributable to the surface hydrophilicity of the F127 layer. These strategies open up the exciting possibility of using F127 in synthesis of gold nanomaterials of variable morphology, and provide a promising platform for biomedical applications in future. 
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