CSIRO Publishing blank image blank image blank image blank imageBooksblank image blank image blank image blank imageJournalsblank image blank image blank image blank imageAbout Usblank image blank image blank image blank imageShopping Cartblank image blank image blank image You are here: Journals > Australian Journal of Chemistry   
Australian Journal of Chemistry
Journal Banner
  An international journal for chemical science
 
blank image Search
 
blank image blank image
blank image
 
  Advanced Search
   

Journal Home
About the Journal
Editorial Board
Contacts
For Advertisers
Content
Online Early
Current Issue
Just Accepted
All Issues
Virtual Issues
Special Issues
Research Fronts
Sample Issue
Covers
For Authors
General Information
Notice to Authors
Submit Article
Open Access
For Referees
Referee Guidelines
Review Article
For Subscribers
Subscription Prices
Customer Service
Print Publication Dates

blue arrow e-Alerts
blank image
Subscribe to our Email Alert or RSS feeds for the latest journal papers.

red arrow Connect with us
blank image
facebook twitter youtube

Affiliated with RACI

Royal Australian Chemical Institute
Royal Australian
Chemical Institute


 

Article << Previous     |     Next >>   Contents Vol 66(5)

Transition-Metal Supramolecular Complexes with 2-Phenylacetate and a Bent Dipyridyl Ligand: In Situ Hydrothermal Syntheses, Crystal Structures, and Photoluminescent Properties

Wei Guo A, Li-Qiang Han A and Ya-Mei Guo A B

A Department of Chemistry, Tianjin University, Tianjin 300072, China.
B Corresponding author. Email: ymguo@tju.edu.cn

Australian Journal of Chemistry 66(5) 539-547 http://dx.doi.org/10.1071/CH12483
Submitted: 22 October 2012  Accepted: 13 December 2012   Published: 20 February 2013


 
PDF (1.4 MB) $25
 Supplementary Material
 Export Citation
 Print
  
Abstract

This work presents seven CoII, CdII, ZnII, MnII, and NiII supramolecular complexes synthesised by hydrothermal reactions from a bent dipyridyl ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (4-bpo) and 2-phenylmalonic acid (2-phmalH2). Interestingly, the in situ generation of 2-phenylacetic acid (Hpa) by decarboxylation of the 2-phenylmalonic acid precursor is observed in all the complexes. Single-crystal X-ray diffraction reveals that these complexes display a variety of 1D (for 27) and monomeric (for 1) coordination motifs, which are further extended into polymeric supramolecular architectures by multiple secondary interactions, such as hydrogen bonding and aromatic stacking. The results evidently demonstrate that the structures of 17 are significantly affected by the metal centres and the counter anions of inorganic salts. The photoluminescence properties of complexes 17 have also been investigated and discussed.





References

[1]  J. R. Li, J. Sculley, H. C. Zhou, Chem. Rev. 2012, 112, 869.
         | CrossRef | CAS |

[2]  R. E. Morris, X. Bu, Nat. Chem. 2010, 2, 353.
         | CrossRef | CAS |

[3]  B. L. Chen, S. C. Xiang, G. D. Qian, Acc. Chem. Res. 2010, 43, 1115.
         | CrossRef | CAS |

[4]  B. Xu, X. Lin, Z. Z. He, Z. J. Lin, R. Cao, Chem. Commun. 2011, 47, 3766.
         | CrossRef | CAS |

[5]  T. Kashiwagi, F. Amemiya, T. Fuchigami, M. Atobe, Chem. Commun. 2012, 48, 2806.
         | CrossRef | CAS |

[6]  O. Chepelin, J. Ujma, P. E. Barran, P. J. Lusby, Angew. Chem. Int. Ed. 2012, 51, 4194.
         | CrossRef | CAS |

[7]  G. Férey, Chem. Soc. Rev. 2008, 37, 191.
         | CrossRef |

[8]  M. J. Zaworotko, Nature 2008, 451, 410.
         | CrossRef | CAS |

[9]  S. M. Neville, G. J. Halder, K. W. Chapman, M. B. Duriska, B. Moubaraki, K. S. Murray, C. J. Kepert, J. Am. Chem. Soc. 2009, 131, 12106.
         | CrossRef | CAS |

[10]  X. D. Chen, X. H. Zhao, M. Chen, M. Du, Chem. – Eur. J. 2009, 15, 12974.
         | CrossRef | CAS |

[11]  F. S. Guo, J. D. Leng, J. L. Liu, Z. S. Meng, M. L. Tong, Inorg. Chem. 2012, 51, 405.
         | CrossRef | CAS |

[12]  G. G. Shan, H. B. Li, H. T. Cao, D. X. Zhu, P. Li, Z. M. Su, Y. Liao, Chem. Commun. 2012, 48, 2000.
         | CrossRef | CAS |

[13]  D. F. Weng, Z. M. Wang, S. Gao, Chem. Soc. Rev. 2011, 40, 3157.
         | CrossRef | CAS |

[14]  H. Y. Zhao, Z. Jin, H. M. Su, X. F. Jing, F. X. Sun, G. S. Zhu, Chem. Commun. 2011, 47, 6389.
         | CrossRef | CAS |

[15]  Y. X. Hu, S. C. Xiang, W. W. Zhang, Z. X. Zhang, L. Wang, J. F. Bai, B. L. Chen, Chem. Commun. 2009, 7551.
         | CrossRef | CAS |

[16]  S. Kitagawa, K. Uemura, Chem. Soc. Rev. 2005, 34, 109.
         | CrossRef | CAS |

[17]  S. T. Zheng, M. H. Wang, G. Y. Yang, Inorg. Chem. 2007, 46, 9503.
         | CrossRef | CAS |

[18]  C. P. Li, X. H. Zhao, X. D. Chen, Q. Yu, M. Du, Cryst. Growth Des. 2010, 10, 5034.
         | CrossRef | CAS |

[19]  Y. Z. Zheng, Y. B. Zhang, M. L. Tong, W. Xue, X. M. Chen, Dalton Trans. 2009, 1396.
         | CrossRef | CAS |

[20]  L. X. Sun, Y. Qi, Y. X. Che, S. R. Batten, J. M. Zheng, Cryst. Growth Des. 2009, 9, 2995.
         | CrossRef | CAS |

[21]  D. Sun, F. J. Liu, R. B. Huang, L. S. Zheng, Inorg. Chem. 2011, 50, 12393.
         | CrossRef | CAS |

[22]  Y. L. Gai, F. L. Jiang, K. C. Xiong, L. Chen, D. Q. Yuan, L. J. Zhang, K. Zhou, M. C. Hong, Cryst. Growth Des. 2012, 12, 2079.
         | CrossRef | CAS |

[23]  X. M. Chen, M. L. Tong, Acc. Chem. Res. 2007, 40, 162.
         | CrossRef |

[24]  Z. J. Lin, M. L. Tong, Coord. Chem. Rev. 2011, 255, 421.
         | CrossRef | CAS |

[25]  D. F. Weng, W. H. Mu, X. J. Zheng, D. C. Fang, L. P. Jin, Inorg. Chem. 2008, 47, 1249.
         | CrossRef | CAS |

[26]  D. Liu, Z. G. Ren, H. X. Li, Y. Chen, J. Wang, Y. Zhang, J. P. Lang, CrystEngComm 2010, 12, 1912.
         | CrossRef | CAS |

[27]  J. H. Cui, L. F. Huang, Z. Z. Lu, Y. Z. Li, Z. J. Guo, H. G. Zhen, CrystEngComm 2012, 14, 2258.
         | CrossRef | CAS |

[28]  C. P. Li, M. Du, Chem. Commun. 2011, 47, 5958.
         | CrossRef | CAS |

[29]  Y. Z. Zheng, M. L. Tong, X. M. Chen, New J. Chem. 2004, 28, 1412.
         | CrossRef | CAS |

[30]  J. Tao, Y. Zhang, M. L. Tong, X. M. Chen, T. Yuen, C. L. Lin, X. Y. Huang, J. Li, Chem. Commun. 2002, 1342.
         | CrossRef | CAS |

[31]  Y. Z. Zheng, M. L. Tong, X. M. Chen, J. Mol. Struct. 2006, 796, 9.
         | CrossRef | CAS |

[32]  J. G. Lin, Y. Su, Z. F. Tian, L. Qiu, L. L. Wen, Z. D. Lu, Y. Z. Li, Q. J. Meng, Cryst. Growth Des. 2007, 7, 2526.
         | CrossRef | CAS |

[33]  L. F. Ma, L. Y. Wang, Y. Y. Wang, M. Du, J. G. Wang, CrystEngComm 2009, 11, 109.
         | CrossRef | CAS |

[34]  M. Nagarathinam, J. J. Vittal, Chem. Commun. 2008, 438.
         | CrossRef | CAS |

[35]  M. Du, X. J. Jiang, X. J. Zhao, Inorg. Chem. 2007, 46, 3984.
         | CrossRef | CAS |

[36]  M. Du, X. J. Jiang, X. J. Zhao, Inorg. Chem. 2006, 45, 3998.
         | CrossRef | CAS |

[37]  J. Chen, C. P. Li, M. Du, CrystEngComm 2011, 13, 1885.
         | CrossRef | CAS |

[38]  M. Du, Z. H. Zhang, C. P. Li, J. Ribas-Ariño, N. Aliaga-Alcalde, J. Ribas, Inorg. Chem. 2011, 50, 6850.
         | CrossRef | CAS |

[39]  C. P. Li, J. Chen, M. Du, CrystEngComm 2010, 12, 4392.
         | CrossRef | CAS |

[40]  C. P. Li, Q. Yu, J. Chen, M. Du, Cryst. Growth Des. 2010, 10, 2650.
         | CrossRef | CAS |

[41]  M. Du, Q. Wang, C. P. Li, X. J. Zhao, J. Ribas, Cryst. Growth Des. 2010, 10, 3285.
         | CrossRef | CAS |

[42]  M. Du, X. H. Bu, Bull. Chem. Soc. Jpn. 2009, 82, 539.
         | CrossRef | CAS |

[43]  A. L. Spek, J. Appl. Cryst. 2003, 36, 7.
         | CrossRef | CAS |

[44]  A. W. Addison, T. N. Rao, J. Reedijk, J. V. Rijn, G. C. Verschoor, J. Chem. Soc., Dalton Trans. 1984, 1349.
         | CrossRef | CAS |

[45]  M. Du, C. P. Li, C. S. Liu, S. M. Fang, Coord. Chem. Rev.

[46]  M. D. Allendorf, C. A. Bauer, R. K. Bhakta, R. J. T. Houk, Chem. Soc. Rev. 2009, 38, 1330.
         | CrossRef | CAS |

[47]  F. Bentiss, M. Lagrenee, J. Heterocycl. Chem. 1999, 36, 1029.
         | CrossRef | CAS |

[48]  SAINT Software Reference Manual 1998 (Bruker AXS: Madison, WI).

[49]  G. M. Sheldrick, SHELXTL NT Version 5.1., Program for Solution and Refinement of Crystal Structures 1997 (University of Göttingen: Göttingen).


   
Subscriber Login
Username:
Password:  

 


    
Legal & Privacy | Contact Us | Help

CSIRO

© CSIRO 1996-2014