CSIRO Publishing blank image blank image blank image blank imageBooksblank image blank image blank image blank imageJournalsblank image blank image blank image blank imageAbout Usblank image blank image blank image blank imageShopping Cartblank image blank image blank image You are here: Journals > Australian Journal of Chemistry   
Australian Journal of Chemistry
Journal Banner
  An international journal for chemical science
blank image Search
blank image blank image
blank image
  Advanced Search

Journal Home
About the Journal
Editorial Structure
For Advertisers
Online Early
Current Issue
Just Accepted
All Issues
Virtual Issues
Special Issues
Research Fronts
Sample Issue
For Authors
General Information
Submit Article
Author Instructions
Open Access
For Referees
Referee Guidelines
Review an Article
For Subscribers
Subscription Prices
Customer Service
Print Publication Dates
Library Recommendation

blue arrow e-Alerts
blank image
Subscribe to our Email Alert or RSS feeds for the latest journal papers.

red arrow Connect with us
blank image
facebook twitter logo LinkedIn

Affiliated with RACI

Royal Australian Chemical Institute
Royal Australian
Chemical Institute


Article << Previous     |     Next >>   Contents Vol 40(11)

Lewis-Base Adducts of Group-11 Metal(I) Compounds. XXX. 3:1 Complexes of Triphenylphosphine With Silver(I) Halides

LM Engelhardt, PC Healy, VA Patrick and AH White

Australian Journal of Chemistry 40(11) 1873 - 1880
Published: 1987


3 : 1 adducts of triphenylphosphine, PPh3, with silver halides, AgX, have been characterized for chloride, bromide and iodide by single-crystal X-ray structure determinations, the chloride as its diacetone solvate. Crystals of the chloride, [(PPh3)3AgCl].2(CH3)2CO, are triclinic, P1, a 13.654(4), b 14.059(4), c 13.970(4) Å, α 84.82(2), β 87.71(2), γ 75.68(2)º, Z 2; the structure was refined to a residual R of 0.061 for No = 2428 independent 'observed' reflections. Crystals of the bromide, [(PPh3)3AgBr], are trigonal, P3, a l9.366(6), c 10.787(6) Å, Z 3, R was 0.054 for No = 2362. Crystals of the iodide, [(PPh3)3AgI], are monoclinic, P2l/n, a 18.993(8), b 13.807(4), c 17.781(8) Å, β 96.11(4)º, Z 4; R was 0.042 for No = 3691. Ag-Cl, Br, I respectively are 2.533(4), 2.671(6)-2.691(4) and 2.858(1) Å. Ag-P for each of the three structures respectively lie in the ranges 2.558(5)-2.582(4), 2.528(3)-2.549(7)and 2.544(2)-2.780(3) Å.

Full text doi:10.1071/CH9871873

© CSIRO 1987

blank image
Subscriber Login

PDF (475 KB) $25
 Export Citation

Legal & Privacy | Contact Us | Help


© CSIRO 1996-2016