The Synthesis and Some Properties of the First Boron-Stabilized Alkenyl Carbanions
A Pelter, K Smith, DE Parry and KD Jones
Australian Journal of Chemistry
45(1) 57 - 70
Calculations indicate a high degree of stabilization of H2BC=CH2 and that it has an allene -type structure H2B=C=CH2. Routes to boron-stabilized alkenyl carbanions have been established for the first time, and alkylation and protonation studies are described.
Full text doi:10.1071/CH9920057
© CSIRO 1992