A Polyfunctional Lewis Acid with Antifacial µ3 -N ,N -Dimethylformamide Ligands in [(o -HgC6 F4 )3 (dmf)2 ]
J. Baldamus,
G. B. Deacon, E. Hey-Hawkins, P. C. Junk and C. Martin
Australian Journal of Chemistry
55(3) 195 - 198
Published: 26 June 2002
Abstract
In [(o-HgC6F4)3(dmf)2], the cyclotrimeric tetrafluoro-o-phenylenemercury(II) molecule is ligated by two m3-dmf-O molecules above (Hg-O 2.837(7), 2.895(5), 3.036(5) Å) and below (Hg-O 2.820(5), 2.863(6), 2.927(6) Å) the Hg3 plane with the two oxygens and the three mercury atoms in a trigonal bipyramidal arrangement about the centroid of the Hg3 plane.https://doi.org/10.1071/CH02039
© CSIRO 2002
