Structural Definition of the Low-Temperature Phase Transition of Tris(ethane-1,2-diamine)zinc(II) Dinitrate

Abstract

The 93 K X-ray crystal structure of tris(ethane-1,2-diamine)zinc(II) dinitrate is reported. As predicted by the spectroscopic studies of other workers, there is a reversible phase transition of the structure at low temperature. We have determined this temperature to be 143 K. The structure at this temperature and below resembles that of the room temperature structure, except the crystallographic D₃ symmetry of the complex cation (296 K) is lowered to C₂ (below 144 K) by subtle changes in cation–anion hydrogen bonding. No change in the conformation of the cation or its bond lengths and angles was found.