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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Iron(iii) Fluoride: A Highly Efficient and Versatile Catalyst for the Protection of Carbonyl Compounds under Solvent-Free Conditions

Babasaheb P. Bandgar A , Vinod T. Kamble A B and Ashwini Kulkarni A
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A Organic Chemistry Research Laboratory, School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, India.

B Corresponding author. Email: vtkd@rediffmail.com

Australian Journal of Chemistry 58(8) 607-610 https://doi.org/10.1071/CH05067
Submitted: 3 March 2005  Accepted: 5 July 2005   Published: 31 August 2005

Abstract

Carbonyl compounds are successfully converted into oxathioacetals and dithioacetals with 2-mercaptoethanol and ethane-1,2-dithiol using a catalytic amount of iron(iii) fluoride under solvent-free conditions. The catalysts were recovered and reused in various runs without affecting the efficiency of the process.


References


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[2]   (a) E. J. Corey, D. Seebach, J. Org. Chem. 1966, 31,  4097.
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