Electrooxidative Cyclization of Hydroquinolyl Alcohols, Hydroquinolylamines, and Dimethyl Aminomalonates

Mitsuhiro Okimoto; Takashi Yoshida; Masayuki Hoshi; Kazuyuki Hattori; Masashi Komata; Kaori Numata; Kenta Tomozawa

doi:10.1071/CH07010

RESEARCH ARTICLE

Electrooxidative Cyclization of Hydroquinolyl Alcohols, Hydroquinolylamines, and Dimethyl Aminomalonates

Mitsuhiro Okimoto ^A ^B , Takashi Yoshida ^A , Masayuki Hoshi ^A , Kazuyuki Hattori ^A , Masashi Komata ^A , Kaori Numata ^A and Kenta Tomozawa ^A

+ Author Affiliations

- Author Affiliations

^A Department of Applied and Environmental Chemistry, Kitami Institute of Technology, Koen-cho 165, Kitami, Hokkaido 090-8507, Japan.

^B Corresponding author. Email: oki@chem.kitami-it.ac.jp

Australian Journal of Chemistry 60(4) 236-242 https://doi.org/10.1071/CH07010
Submitted: 15 January 2007 Accepted: 13 March 2007 Published: 26 April 2007

Abstract

Several hydroquinolyl alcohols and amines were electrochemically oxidized in methanol in the presence of sodium methoxide and potassium iodide to afford the corresponding intramolecular cyclization products. Furthermore, several amino malonates were electrochemically oxidized to yield the corresponding heterocyclic compounds through an intramolecular carbon–carbon bond formation in the presence of sodium cyanide in methanol.

References

Electrooxidative Cyclization of Hydroquinolyl Alcohols, Hydroquinolylamines, and Dimethyl Aminomalonates

Abstract

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