Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Novel Acentric Organic Solids with Non-linear Optical and Ferroelectric Properties

Yong-Tao Wang A C , Gui-Mei Tang A , Tian-Duo Li A , Jian-Chao Yu A , Yong-Qin Wei B , Ji-Bei Ling B and Xi-Fa Long B C
+ Author Affiliations
- Author Affiliations

A Department of Chemical Engineering, Shandong Institute of Light Industry, Jinan, 250353, China.

B Fujian Institute of Research on the Structure of Mater, Chinese Academy of Science, Fuzhou, Fujian, 350002, China.

C Corresponding authors. Email: ceswyt@sohu.com; lxf@fjirsm.ac.cn

Australian Journal of Chemistry 63(2) 336-342 https://doi.org/10.1071/CH09277
Submitted: 10 May 2009  Accepted: 20 August 2009   Published: 26 February 2010

Abstract

A series of compounds obtained through one-pot three-component reaction, present non-centrosymmetric polar packing arrangement, resulting in strong second harmonic generation responses and ferroelectric behaviours.


Acknowledgements

This work was financially supported by the Project of Shandong Province Higher Educational Service and Technology Program (J09LB03), and the Starting Funding of Shandong Institute of Light Industry (to Dr. Yong-Tao Wang), and the Project of Fujian Province (2007F3115). We thank Mr. Xiao-Jun Jiang and Zhen-Wei Qiang for experimental help.


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[10]   Crystal data for 1 (C21H22N2O): orthorhombic, space group Pna21, Mr = 318.41, a = 16.8749(3), b = 14.7594(2), c = 6.8539(1) Å, β = 90°, V = 1707.06(5) Å3, Z = 4, ρcalcd = 1.239 g cm–3, μ = 0.077 mm–1, R1 = 0.0402, wR2 = 0.1009, GOF = 1.00 for all data, Flack x = 0.1(2); Crystal data for 2 (C21H22N2O): monoclinic, space group Cc, Mr = 318.41, a = 14.7371(17), b = 16.6050(18), c = 6.9631(8) Å, β = 91.337(2)°, V = 1703.5(3) Å3, Z = 4, ρcalcd = 1.242 g cm–3, μ = 0.077 mm–1, R1 = 0.0442, wR2 = 0.1114, GOF = 1.02 for all data, Flack x = –1.8(2); Crystal data for 3 (C22H22N2O3): orthorhombic, space group Pna21, Mr = 362.42, a = 10.3939(8), b = 15.4715(12), c = 11.7267(9) Å, V = 1885.8(3) Å3, Z = 4, ρcalcd = 1.276 g cm–3, μ = 0.086 mm–1, R1 = 0.0395, wR2 = 0.1168, Flack x = 1.2(1), GOF = 1.03 for all data. CCDC reference number 632217–632219. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223–336–033; or deposit@ccdc.cam.ac.uk). As the crystals contain only non-heavy atoms, the Flack parameters for both absolute configurations are essentially meaningless and were not refined.

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