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Contents Vol 64(5)

Homo and Heterocoupling of Terminal Alkynes Using Catalytic CuCl2 and DBU

Rengarajan Balamurugan A B , Naganaboina Naveen A , Seetharaman Manojveer A and Masthan Vali Nama A
+ Author Affiliations
- Author Affiliations

A School of Chemistry, University of Hyderabad, Gachibowli, Hyderabad 500046, India.

B Corresponding author. Email: rbsc@uohyd.ernet.in

Australian Journal of Chemistry 64(5) 567-575 https://doi.org/10.1071/CH11080
Submitted: 17 February 2011  Accepted: 5 April 2011   Published: 30 May 2011

Abstract

Homocoupling of terminal alkynes has been efficiently achieved using catalytic amounts of CuCl2 and DBU. This methodology could be extended to couple two different terminal alkynes together by taking one of the alkyne partners, preferably the electron rich alkyne, in five fold excess than the other.


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