Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Shopping Cart: ( empty )
You are here: Home > Journals > CH > CH11395
RESEARCH FRONT
Contents Vol 65(7)

Synthesis and Structure of a Dimeric, Anionic Thioglycolate Derivative of Manganese Carbonyl1

Yuan Dai A and Brian K. Nicholson A B
+ Author Affiliations
- Author Affiliations

A Chemistry Department, Faculty of Science and Engineering, University of Waikato, Hamilton 3240, New Zealand.

B Corresponding author. Email: b.nicholson@waikato.ac.nz

Australian Journal of Chemistry 65(7) 730-733 https://doi.org/10.1071/CH11395
Submitted: 14 October 2011  Accepted: 8 November 2011   Published: 30 November 2011

Abstract

The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn2(thioglycolate)2(CO)6]2–. This was isolated as the Et3NH+ salt and fully characterized for comparison with the previously reported thiosalicylate analogue.


References

[1]  C. V. Depree, L. Main, B. K. Nicholson, K. Roberts, J. Organomet. Chem. 1996, 517, 201.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK28XjtlWjtrc%3D&md5=455235e9f662d1b222c4b55ae25156bcCAS |

[2]  (a) L. J. McCaffrey, W. Henderson, B. K. Nicholson, J. E. Mackay, M. B. Dinger, J. Chem. Soc., Dalton Trans. 1997, 2577.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2sXlsF2js70%3D&md5=ce773779c3066cb33b9d01f6c14e9a63CAS |
      (b) L. J. McCaffrey, W. Henderson, B. K. Nicholson, Polyhedron 1998, 17, 221.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) W. Henderson, L. J. McCaffrey, B. K. Nicholson, J. Chem. Soc., Dalton Trans. 2000, 2753.
         | Crossref | GoogleScholarGoogle Scholar |
      (d) W. Henderson, B. K. Nicholson, A. G. Oliver, C. E. F. Rickard, J. Organomet. Chem. 2001, 625, 40.
         | Crossref | GoogleScholarGoogle Scholar |
      (e) W. Henderson, B. K. Nicholson, S. J. Faville, D. Fan, J. D. Ranford, J. Organomet. Chem. 2001, 631, 41.
         | Crossref | GoogleScholarGoogle Scholar |
      (f) W. Henderson, B. K. Nicholson, Inorg. Chim. Acta 2004, 357, 2231.
         | Crossref | GoogleScholarGoogle Scholar |

[3]  A. Bader, E. Lindner, Coord. Chem. Rev. 1991, 108, 27.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK3MXitF2qur8%3D&md5=3e661c01772af9397701d0fd2f268883CAS |

[4]  (a) L. Ma, S. Liu, H. Zhu, J. Zubieta, Polyhedron 1989, 8, 669.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL1MXks12ks70%3D&md5=117fe02c1585e08f3fc941dda8d1ec61CAS |
      (b) W. Yang, C. Lu, S. Lu, H. Zhang, Helv. Chim. Acta 2002, 85, 2417.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) T. Yonemura, K. Shibuya, K.-I. Okamoto, T. Ama, H. Kawaguchi, T. Yasui, Inorg. Chim. Acta 1997, 260, 119.
         | Crossref | GoogleScholarGoogle Scholar |
      (d) R. C. Elder, L. R. Florian, R. E. Lake, A. M. Yacynych, Inorg. Chem. 1973, 12, 2690.
         | Crossref | GoogleScholarGoogle Scholar |
      (e) A. Cervilla, E. Liopis, J. A. Ramirez, A. Domenech, P. Palanca, M. R. Picher, C. A. Ghilardi, A. Oriandini, J. Chem. Soc., Dalton Trans. 1994, 175.
         | Crossref | GoogleScholarGoogle Scholar |

[5]  W. Henderson, T. D. Kilpin, B. K. Nicholson, Struct. Chem. 2008, 19, 199.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXotVyru78%3D&md5=e4133445e7ecfd254781ff7357958581CAS |

[6]  (a) S. Jeannin, Y. Jeannin, G. Lavigne, Inorg. Chem. 1978, 17, 2103.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaE1cXkvVeqtb4%3D&md5=4be6291f0bcc68be9bed65de2c1d1348CAS |
      (b) C. Li, W. K. Leong, J. Organomet. Chem. 2008, 693, 1292.
         | Crossref | GoogleScholarGoogle Scholar |

[7]  (a) B. Zhuang, L. Huang, Y. Yang, J. Lu, Inorg. Chim. Acta 1986, 116, L41.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL2sXis1ynug%3D%3D&md5=8345a9470edd2df47f077c15bdb9f9b4CAS |
      (b) J. T. Liu, Y. C. Du, L. Zhang, Y. J. Mao, Y. L. Wu, Acta Crystallogr. 2006, E62, m237.
      (c) M. El-khateeb, H. Goris, W. Weigard, Inorg. Chim. Acta 2007, 360, 705.
         | Crossref | GoogleScholarGoogle Scholar |

[8]  R. B. King, Organometal. Synth 1965, 1, 174.

[9]  R. H. Blessing, Acta Crystallogr. 1995, A51, 33.
         | 1:CAS:528:DyaK2MXjslWhsbc%3D&md5=ae5c98cae738467b22e3f4963c59dd89CAS |

[10]     (a) (a) G. M. Sheldrick, SHELX97 – Programs for Solving and Refining X-ray Structures 1997 (University of Gottingen: Gottingen, Germany).
      (b) G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112.

[11]  S. Ghosh, F. K. Camellia, K. Fatema, M. I. Hossain, M. R. Al-Mamun, G. M. G. Hossain, G. Hogarth, S. E. Kabir, J. Organomet. Chem. 2011, 696, 2935. and references cited therein
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXptVajtr0%3D&md5=451bcecd49e2a9ab7eb8500f437ad8f1CAS |