Star Polymers of Sodium Styrenesulfonate Prepared by One-Pot TEMPO-Controlled SFRP
Jianfu Ding A B and Steven Holdcroft A C
+ Author Affiliations
- Author Affiliations
A Department of Chemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.
B Current address: Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, ON, K1A 0R6, Canada.
C Corresponding author. Email: holdcrof@sfu.ca
Australian Journal of Chemistry 65(8) 1117-1123 https://doi.org/10.1071/CH12176
Submitted: 30 March 2012 Accepted: 20 May 2012 Published: 14 June 2012
Abstract
Star polymers of sodium styrenesulfonate with controlled arm length were prepared in a one-pot polymerization. Sodium styrenesulfonate was first polymerized with controlled molecular weight and narrow polydispersity by stable free radical polymerization. Poly(sodium styrenesulfonate) was terminated with divinyl benzene and star polymers prepared via stable free radical coupling of vinylic terminal groups. Star polymers based on arms of 20 and 32 repeat units possessed ~33 and ~41 arms per star respectively. Formation of star polymers with much longer arms was limited by poor coupling kinetics.
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