Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Shopping Cart: ( empty )
You are here: Home > Journals > CH > CH13251
RESEARCH ARTICLE
Contents Vol 66(11)

Five bis(imidazole)-based Coordination Polymers Tuned by Central Metal Ions and S-containing Dicarboxylates: Syntheses, Structures, and Properties

Xiu-Li Wang A B , Yun Qu A , Guo-Cheng Liu A , Jing-Jing Huang A , Nai-Li Chen A and Hong-Yan Lin A
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Bohai University, Liaoning Province Silicon Materials Engineering Technology Research Centre, Jinzhou 121000, China.

B Corresponding author. Email: wangxiuli@bhu.edu.cn

Australian Journal of Chemistry 66(11) 1370-1377 https://doi.org/10.1071/CH13251
Submitted: 15 May 2013  Accepted: 28 June 2013   Published: 10 September 2013

Abstract

Five new coordination polymers, namely [Zn(2-CMSN)(biim-4)] (1), [Co2(2-CMSN)2(biim-4)(H2O)4] (2), [Ni(2-CMSN)(biim-4)0.5(H2O)2] (3), [Cd(2-CMSN)(biim-4)0.5(H2O)2] (4), and [Cd(ADTZ)(biim-4)1.5]·5H2O (5), (2-H2CMSN = 2-carboxymethylsulfanyl nicotinic acid, H2ADTZ = 2,5-(S-acetic acid) dimercapto-1,3,4-thiadiazole, biim-4 = 1,1′-(1,4-butanediyl)bis(imidazole)) have been synthesised under hydrothermal conditions and structurally characterised by single-crystal X-ray diffraction analysis, infrared spectroscopy, elemental analysis, thermogravimetric analysis, and powder X-ray diffraction. Complex 1 shows a 2D undulated sheet, which is constructed from 1D meso-helical [Zn-(biim-4)]n chains and linear [Zn-(2-CMSN)]n chains. Complexes 2–4 exhibit a similar 2D (4,4) grid network constructed from zigzag [M-(2-CMSN)]n chains and linear [M-(biim-4)]n chains (M = CoII, NiII and CdII), which possesses a ‘4+2’ type six-membered ring. Complex 5 displays a 3D architecture derived from 2D Cd-(biim-4) layers and double ADTZ linkers with diamond-type 66 topology. The effects of the central metals and S-containing dicarboxylates on the structures of the title coordination polymers have been discussed. The luminescent properties of complexes 1, 4, and 5 have been studied. Complex 5 exhibits photocatalytic activity for dye degradation under ultraviolet light and good stability towards photocatalysis.


References

[1]  L. Pan, M. B. Sander, X. Y. Huang, J. Li, M. Smith, E. Bittner, B. Bockrath, J. K. Johnson, J. Am. Chem. Soc. 2004, 126, 1308.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2cXksFClsA%3D%3D&md5=2aec40fc6eb6108489926fd75bb10183CAS | 14759166PubMed |

[2]  B. L. Chen, L. B. Wang, Y. Q. Xiao, F. R. Fronczek, M. Xue, Y. J. Cui, G. D. Qian, Angew. Chem. Int. Ed. 2009, 48, 500.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXht12isL0%3D&md5=e9addc32a510d771047765ac0bf45f2aCAS |

[3]  L. J. Murray, M. Dinca, J. R. Long, Chem. Soc. Rev. 2009, 38, 1294.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXkvVamuro%3D&md5=f5f8c1034809909f5d2f8d044e3cdab1CAS | 19384439PubMed |

[4]  S. S. Chen, M. Chen, S. Takamizawa, P. Wang, G. C. Lv, W. Y. Sun, Chem. Commun. 2011, 47, 4902.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXkslKhs7Y%3D&md5=720bedc8d497c74fe98e5a64819d936dCAS |

[5]  H. W. Roesky, M. Andruh, Coord. Chem. Rev. 2003, 236, 91.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXkvVyqsw%3D%3D&md5=f495edd0921bee8cb834c5f6a24e730dCAS |

[6]  J. R. Li, Q. Yu, E. C. Sanudo, Y. Tao, X. H. Bu, Chem. Commun. 2007, 25, 2602.
         | Crossref | GoogleScholarGoogle Scholar |

[7]  Y. Y. Liu, J. Li, J. F. Ma, J. C. Ma, J. Yang, CrystEngComm 2012, 14, 169.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXhsFKkt7fL&md5=26bebb7e828fee2b9305d42313d1ec34CAS |

[8]  Z. B. Han, X. N. Cheng, X. M. Chen, Cryst. Growth Des. 2005, 5, 695.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2cXnvFGhu7Y%3D&md5=a11d3a220e2ec9f1c3df5de1b1f53ddaCAS |

[9]  Q. Chu, G. X. Liu, Y. Q. Huang, X. F. Wang, W. Y. Sun, Dalton Trans. 2007, 4302.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXhtVOrt7bM&md5=29a5767348dbf34c9bbd8bb5b3cc61c4CAS | 17893820PubMed |

[10]  L. P. Zhang, J. Yang, J. F. Ma, Z. F. Jia, Y. P. Xie, G. H. Wei, CrystEngComm 2008, 10, 1410.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXht1amt77O&md5=e1575cf62e1684d94ca9f138602c29f8CAS |

[11]  Y. Ma, A. L. Cheng, J. Y. Zhang, Q. Yue, E. Q. Gao, Cryst. Growth Des. 2009, 9, 867.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXhsVGnsLjM&md5=5ad3c05e86f55a917d77df218e9f5770CAS |

[12]  S. N. Wang, J. F. Bai, H. Xing, Y. Z. Li, Y. Song, Y. Pan, M. Scheer, X. Z. You, Cryst. Growth Des. 2007, 7, 747.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXisVajtrg%3D&md5=f649473d243154e42341db24b53a5d82CAS |

[13]  M. Du, X. J. Jiang, X. J. Zhao, Inorg. Chem. 2007, 46, 3984.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXkt1Sitrs%3D&md5=3a471402ec9ef04e29b81d3cd042b29eCAS | 17432846PubMed |

[14]  Y. Q. Chen, S. J. Liu, Y. W. Li, G. R. Li, K. H. He, Y. K. Qu, T. L. Hu, X. H. Bu, Cryst. Growth Des. 2012, 12, 5426.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38Xhtl2rt73K&md5=e3fd562a0412a3f5c1e4683ae89277faCAS |

[15]  L. M. Zhao, Z. J. Zhang, S. Y. Zhang, P. Cui, W. Shi, B. Zhao, P. Cheng, D. Z. Liao, S. P. Yan, CrystEngComm 2011, 13, 907.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXitVCiu7o%3D&md5=bd9ca82cbedd8dbce9d5ccdff3176023CAS |

[16]  X. L. Wang, Y. Qu, G. C. Liu, J. Luan, H. Y. Lin, Inorg. Chim. Acta 2013, 399, 105.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXjtVGnu7g%3D&md5=26dd96fcafd6341ee90032eba1d7812eCAS |

[17]  G. H. Cui, J. R. Li, J. L. Tian, X. H. Bu, S. R. Batten, Cryst. Growth Des. 2005, 5, 1775.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXmtVChu78%3D&md5=6a3c6d77fcc16dd11003956689b24c82CAS |

[18]  X. R. Jiang, X. J. Wang, Y. L. Feng, Inorg. Chim. Acta 2012, 383, 38.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XisVyhtLo%3D&md5=1613c968e4e268ddb38906fe981b1e4eCAS |

[19]  C. J. Wang, H. R. Ma, Y. Y. Wang, P. Liu, L. J. Zhou, Q. Z. Shi, S. M. Peng, Cryst. Growth Des. 2007, 7, 1811.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXot1ahtrc%3D&md5=a6c376b3cad41562a709225791bf9331CAS |

[20]  W. L. Liu, J. H. Yu, J. X. Jiang, L. M. Yuan, B. Xu, Q. Liu, B. T. Qu, G. Q. Zhang, C. G. Yan, CrystEngComm 2011, 13, 2764.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXkvVansr0%3D&md5=b1b111a999bf7a92c07c75afb2bbfa43CAS |

[21]  J. Z. Gao, J. Yang, Y. Y. Liu, J. F. Ma, CrystEngComm 2012, 14, 8173.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XhsF2rsrjM&md5=61e8692ed378a9124b0bbc1848376a6dCAS |

[22]  H. J. Hao, D. Sun, F. J. Liu, R. B. Huang, L. S. Zheng, Cryst. Growth Des. 2011, 11, 5475.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXhsVWms77L&md5=21e4ea0c6b7b64994ccd09b268c4535eCAS |

[23]  Y. P. Wu, D. S. Li, J. Zhao, Z. F. Fang, W. W. Dong, G. P. Yang, Y. Y. Wang, CrystEngComm 2012, 14, 4745.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XovVynsrw%3D&md5=797c46b7ed4762fe583e0739f3c17ffcCAS |

[24]  Y. Yang, P. Du, J. F. Ma, W. Q. Kan, B. Liu, J. Yang, Cryst. Growth Des. 2011, 11, 5540.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXhsVCrsLvJ&md5=7f4c2713ba171d3a4da67429e8a3f693CAS |

[25]  Y. Qi, F. Luo, S. R. Batten, Y. X. Che, J. M. Zheng, Cryst. Growth Des. 2008, 8, 2806.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXnvFGqt7k%3D&md5=cdd7a2c99cb2d5a053a4580ee3e2464eCAS |

[26]  X. J. Gu, D. F. Xue, Cryst. Growth Des. 2006, 6, 2551.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XhtVSnsbfI&md5=8597a058ec099b70c411256e794c1859CAS |

[27]  X. L. Wang, B. Mu, H. Y. Lin, G. C. Liu, J. Organomet. Chem. 2011, 696, 2313.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXlsVCksrY%3D&md5=ca04eb00a2714f5e2e30fb438090aefaCAS |

[28]  F. Hipler, R. A. Fischer, J. Müller, J. Chem. Soc., Perkin Trans. 2 2002, 2, 1620.

[29]  J. E. McGarrah, Y. J. Kim, M. Hissler, R. Eisenberg, Inorg. Chem. 2001, 40, 4510.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3MXlsVSrsLw%3D&md5=2ae8ce5ec07bd0be44a20b8ce341a97fCAS | 11511190PubMed |

[30]  H. N. Wang, X. Meng, C. Qin, X. L. Wang, G. S. Yang, Z. M. Su, Dalton Trans. 2012, 41, 1047.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXhs1OitrrN&md5=d74eb373c711a11e0a1c3f4e7896b483CAS | 22109695PubMed |

[31]  L. P. Zhang, J. F. Ma, Y. Y. Pang, J. C. Ma, J. Yang, CrystEngComm 2010, 12, 4433.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXhsFWhs7rJ&md5=81e05b91c377bd09f45e30a298f85de7CAS |

[32]  L. L. Wen, Y. Z. Li, Z. D. Lu, J. G. Lin, C. Y. Duan, Q. J. Meng, Cryst. Growth Des. 2006, 6, 530.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28Xhtw%3D%3D&md5=191206e7933a7b96bc714ccea6d22806CAS |

[33]  L. L. Wen, Z. D. Lu, J. G. Lin, Z. F. Tian, H. Z. Zhu, Q. J. Meng, Cryst. Growth Des. 2007, 7, 93.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28Xht12itb7K&md5=52b97979c5f3aa7214be3a847c923907CAS |

[34]  W. Q. Kan, Y. Y. Liu, J. Yang, Y. Y. Liu, J. F. Ma, CrystEngComm 2011, 13, 4256.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXnsFKqt7s%3D&md5=78c783631a0adc4409cc91f15a5dbe70CAS |

[35]  H. Y. Liu, H. Wu, J. F. Ma, Y. Y. Liu, B. Liu, J. Yang, Cryst. Growth Des. 2010, 10, 4795.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXht1ahtb3M&md5=8fd616989191f8aff1fad88c332bfa60CAS |

[36]  T. Wen, D. X. Zhang, J. Zhang, Inorg. Chem. 2013, 52, 12.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XhvVertr3O&md5=d61b3e436e2b4f68104edb4dbc0a3b2aCAS | 23244571PubMed |

[37]  P. Du, Y. Yang, J. Yang, B. K. Liu, J. F. Ma, Dalton Trans. 2013, 42, 1567.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXhsFOmsw%3D%3D&md5=5f146d5e3d80beed9be0a1ad1fa55701CAS | 23138531PubMed |

[38]  W. Q. Kan, B. Liu, J. Yang, Y. Y. Liu, J. F. Ma, Cryst. Growth Des. 2012, 12, 2288.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XlvFCru78%3D&md5=2a471bfbb9972d9b40fa32bd35a85a52CAS |

[39]  X. L. Wang, J. J. Huang, L. L. Liu, G. C. Liu, H. Y. Lin, J. W. Zhang, N. L. Chen, Y. Qu, CrystEngComm 2013, 15, 1960.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXisVaiu7w%3D&md5=f4e6b70fb1b1f5b1dd58b433b5be08d8CAS |

[40]  X. J. Wang, Y. L. Feng, Acta Crystallogr. Sect. E Struct. Rep. Online 2010, 66, 1298.
         | Crossref | GoogleScholarGoogle Scholar |

[41]  X. H. Lou, Y. Zhu, H. Gao, A. X. Zhu, Y. T. Fan, H. W. Hou, H. J. Lu, J. Inorg. Mater. 2005, 21, 716.
         | 1:CAS:528:DC%2BD2MXktF2mtr4%3D&md5=a0b032d3256929927b2c6726623a6e6dCAS |

[42]  J. Yang, J. F. Ma, S. R. Batten, Z. M. Su, Chem. Commun. 2008, 19, 2233.
         | Crossref | GoogleScholarGoogle Scholar |

[43]  G. M. Sheldrick, Acta Crystallogr. A 2008, 64, 112.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXhsVGhurzO&md5=c16dcfe329fce2375df65b1474a83185CAS | 18156677PubMed |