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RESEARCH ARTICLE
Contents Vol 67(6)

A Simple Route to Prepare Zeolite Y Nanosheets with Hierarchical Perfoliate Pores

Daming Cui A B , Bin Zhou A B , Jia Yin A and Meiqing Lou A C
+ Author Affiliations
- Author Affiliations

A Department of Neurosurgery, Shanghai Tenth People’s Hospital, Tongji University School of Medicine, 301 Middle Yanchang, Shanghai 200072, China.

B These authors contributed equally to this study.

C Corresponding author. Email: 8228loumq@tongji.edu.cn

Australian Journal of Chemistry 67(6) 929-932 https://doi.org/10.1071/CH13543
Submitted: 8 October 2013  Accepted: 10 February 2014   Published: 7 March 2014

Abstract

Using the high siliceous zeolite Y crystals (ZY-C) as precursor, zeolite Y nanosheets (ZY-N) with hierarchical perfoliate pores were successfully synthesised via a simple ‘top-down’ approach. The ultra-thin faujasite nanosheets with intact zeolite Y framework and hierarchical micro-meso-macropores were first observed in ZY-N during characterisation. Contrary to the layer assembly process in growing zeolite Y crystals, the breakage and swelling of the energy-poor T–O–T (where T is the tetrahedral atom, Si) bonds within the double six-membered rings (D6R) between the neighbouring faujasite sheets demonstrated the possible principle for the synthesis of ZY-N.


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