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RESEARCH ARTICLE
Contents Vol 67(5)

Synthesis, Structure, and Properties of a New ErIII Iodate

Chun-Yang Pan A B , Hai-Deng Mai A , Wu-Zhou Chen A , Feng-Hua Zhao A and Hong-Mei Yang A
+ Author Affiliations
- Author Affiliations

A School of Light Industry and Chemical Engineering, Guangdong University of Technology, Guangzhou, Guangdong 510006, China.

B Corresponding author. Email: panchuny@gdut.edu.cn

Australian Journal of Chemistry 67(5) 763-767 https://doi.org/10.1071/CH13570
Submitted: 21 October 2013  Accepted: 17 December 2013   Published: 28 January 2014

Abstract

A new iodate Er(IO3)3·2H2O was synthesized under mild hydrothermal conditions. The structure has been confirmed by single-crystal X-ray analysis. It crystallizes in the triclinic system with space group P-1 (No.2), a = 7.338(4) Å, b = 7.506(4) Å, c = 9.409(5) Å, α = 79.698(5)°, β = 85.245(4)°, γ = 71.934(4)°, V = 484.5(5) Å3, Z = 2. Some characterizations were performed such as Fourier transform infrared spectroscopy (FTIR), thermogravimetric–differential scanning calorimetry (TG-DSC) analysis, luminescence spectroscopy, and magnetic property measurements. The overall framework of Er(IO3)3·2H2O is based on one-dimensional chains. The adjacent chains are further linked with each other by hydrogen bonds to form a three-dimensional supramolecular network. The luminescent and magnetic properties of Er(IO3)3·2H2O were studied.


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