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Contents Vol 67(10)

A Three-Component 1D/2D → 2D Interpenetrated Coordination Network: Structure and Gas Adsorption Studies

Jin-Xiang Chen A F , Ni-Ni Ding B , Ming Chen A , Wen-Hua Chen A , David J. Young B E , Wen-Hua Zhang B D F and T. S. Andy Hor B C F
+ Author Affiliations
- Author Affiliations

A School of Pharmaceutical Sciences, Southern Medical University, Guangzhou 510515, China.

B Institute of Materials Research and Engineering (IMRE), A*STAR, 3 Research Link, 117602, Singapore.

C Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore.

D Current address: College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.

E Current address: School of Science, Monash University, 46150 Bandar Sunway, Selangor D. E. 47500, Malaysia.

F Corresponding authors. Email: jxchen@smu.edu.cn; zhangw@imre.a-star.edu.sg; andyhor@nus.edu.sg

Australian Journal of Chemistry 67(10) 1391-1395 https://doi.org/10.1071/CH14111
Submitted: 3 March 2014  Accepted: 24 April 2014   Published: 21 May 2014

Abstract

We herein report a Cd-based coordination polymer containing three integrated polymeric components: two neutral and entangled two-dimensional (6,3) nets and one zwitterionic one-dimensional polymer with corner-sharing double-stranded chains propagating along the c-direction to lock the consecutive ligand struts of the (6,3) nets. Despite a sophisticated entanglement, this coordination polymer is porous to selectively adsorb CO2.


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