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RESEARCH ARTICLE
Contents Vol 68(3)

Two CoII Compounds Showing Interesting Magnetic Properties Modulated by Supramolecular Interactions

Xiao-Min Zhang A , Li-Na Meng A , Jian-Qiang Li A , Xue-Feng Feng A , Ming-Biao Luo A and Feng Luo A B
+ Author Affiliations
- Author Affiliations

A College of Biology, Chemistry and Material Science, East China Institute of Technology, Nanchang, Jiangxi 330013, China.

B Corresponding author. Email: ecitluofeng@163.com

Australian Journal of Chemistry 68(3) 433-440 https://doi.org/10.1071/CH14290
Submitted: 12 May 2014  Accepted: 6 June 2014   Published: 25 August 2014

Abstract

Two new CoII coordination compounds, namely Co[(cis-trans)-L](nip)·H2O (1) and Co[(cis-cis)-L](Hbtc)·2H2O (2) (L = N1,N4-di(pyridin-3-yl)terephthalamide, H2nip = 5-nitroisophthalic acid, H3btc = benzene-1,3,5-tricarboxylic acid), were synthesised hydrothermally and characterised by single crystal X-ray diffraction and direct current magnetic susceptibility measurement. Interestingly, the results disclose somewhat tuneable magnetic properties for compounds 1 and 2, mainly due to the distinct supramolecular interactions.


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