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Contents Vol 67(12)

A Barium Vanadium(v) Selenite Hydrate, Ba(VO2)2(SeO3)2·H2O: A Novel 3D Polymer of Cross-Linked Sheets with Embedded ···V–O–V··· 21 Helices*

Kieryn L. Kilminster A , Francis J. Lincoln A C , Brian W. Skelton A B and Allan H. White A
+ Author Affiliations
- Author Affiliations

A School of Chemistry and Biochemistry, The University of Western Australia M310, Crawley, WA 6009, Australia.

B Centre for Microscopy, Characterisation and Analysis, The University of Western Australia M310, Crawley, WA 6009, Australia.

C Corresponding author. Email: francis.lincoln@uwa.edu.au

Australian Journal of Chemistry 67(12) 1878-1881 https://doi.org/10.1071/CH14473
Submitted: 27 July 2014  Accepted: 25 August 2014   Published: 18 September 2014

Abstract

The characterisation, by a single-crystal X-ray study at ~150 K, of brown acicular crystals of barium(ii) bis(dioxovanadium(v)) bis(selenite(iv)) monohydrate, BaSe2V2O10·H2O, obtained as a minor product of the synthesis of the previously reported ‘Ba(VO)2(SeO3)2(HSeO3)2’, is recorded. Crystals are monoclinic, P21/c, a = 10.803(2), b = 5.1126(8), c = 17.905(3) Å, β = 92.048(2)°, V = 988.3(3) Å3, 2456 independent diffractometer reflections refining to R1 = 0.032, wR2 = 0.084. A single BaV2Se2O11H2 formula unit, devoid of crystallographic symmetry, comprises the asymmetric unit of the structure, which is a three-dimensional polymer, with component sheets parallel to the crystallographic b axis, containing pentavalent vanadium atoms, one five-, the other six-coordinate, linked by selenite pyramids.


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