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RESEARCH ARTICLE
Contents Vol 69(8)

Photoinitiated Synthesis of Sulfides in Water

Sergio A. Rodriguez A , Leandro D. Mena B and Maria T. Baumgartner B C
+ Author Affiliations
- Author Affiliations

A CITSE (CONICET), Instituto de Ciencias Químicas, UNSE, Av. Belgrano Sur 1912, Santiago del Estero (4200), Argentina.

B INFIQC- Dpto. Qca. Orgánica, Fac. Cs. Químicas, Univ. Nac. Córdoba, Ciudad Universitaria. Córdoba (5000), Argentina.

C Corresponding author. Email: tere@fcq.unc.edu.ar

Australian Journal of Chemistry 69(8) 919-924 https://doi.org/10.1071/CH15496
Submitted: 13 August 2015  Accepted: 16 March 2016   Published: 19 April 2016

Abstract

Herein, we report a synthetic route to obtain aryl sulfides using inexpensive and non-toxic reactants and water as solvent, that avoids the use of catalysts or heating. The photoinduced reaction between soluble substrates and a series of thiols in alkaline aqueous medium produces the corresponding sulfides in moderate to good yields.


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