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RESEARCH ARTICLE
Contents Vol 69(10)

An Organobase (TBD)-Anchored Mesoporous Silica Nanoparticle-Catalyzed Green Synthesis of Dihydropyrano[2,3-c]pyrazoles

Bikash Karmakar
+ Author Affiliations
- Author Affiliations

Gobardanga Hindu College, Department of Chemistry, Khantura, North 24 Parganas-743273, India. Email: bikashkarm@gmail.com

Australian Journal of Chemistry 69(10) 1117-1123 https://doi.org/10.1071/CH15812
Submitted: 24 December 2015  Accepted: 20 March 2016   Published: 26 April 2016

Abstract

An efficient, mild, and environmental friendly method has been developed for the synthesis of dihydropyrano[2,3-c]pyrazole in ethanolic water over 1,5,7-triazabicyclo-[4,4,0]-dec-1-ene (TBD)-anchored mesoporous silica nanoparticle catalyst. The method involves the assembly of ethyl acetoacetate, hydrazine hydrate, different aldehydes, and malononitrile. It affords the corresponding product in high yield with short reaction times, while employing a very low loading of catalyst. The catalyst was reused several times without significant loss in activity.


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