Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

A Highly Selective Chemosensor for Naked-Eye Detection of Fluoride and Aluminium(iii) Ions Based on a New Schiff Base Derivative

Masoumeh Orojloo A and Saeid Amani A B
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Faculty of Sciences, Arak University, Dr Beheshti Avenue, Arak 38156-8-8349, Iran.

B Corresponding author. Email: s-amani@araku.ac.ir

Australian Journal of Chemistry 69(8) 911-918 https://doi.org/10.1071/CH15826
Submitted: 31 December 2015  Accepted: 27 February 2016   Published: 4 April 2016

Abstract

A new chromogenic receptor, 4-((2,4-dichlorophenyl)diazenyl)-2-(3-hydroxypropylimino)methyl)phenol, has been designed and synthesized for quantitative and low-cost detection of various biological anions and cations. The dye was characterized by elemental analyses, infrared, UV-visible spectroscopy, and NMR spectroscopy. The chemosensor showed visual changes towards anions, such as F and H2PO4, in DMSO and towards cations, such as Al3+, Cu2+, Fe3+, and Cr3+, in DMSO/water (9 : 1). The anion recognition property of the receptor via proton transfer was monitored by UV-visible titration and 1H NMR spectroscopy. The binding constant (Ka) and stoichiometry of the host–guest complexes formed were determined by the Benesi–Hildebrand (B–H) plot and Job's method, respectively.


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