Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Preparation and Characterization of Copper(ii) and Nickel(ii) Complexes with N-Benzyliminodiacetamide Derivatives

Neven Smrečki A B , Vladimir Stilinović A , Maja Merkaš A , Andrea Lučić A , Boris-Marko Kukovec A and Zora Popović A
+ Author Affiliations
- Author Affiliations

A Laboratory of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia.

B Corresponding author. Email: nsmrecki@chem.pmf.hr

Australian Journal of Chemistry 69(8) 896-904 https://doi.org/10.1071/CH16046
Submitted: 26 January 2016  Accepted: 25 February 2016   Published: 12 April 2016

Abstract

The reactions of substituted N-benzyliminodiacetamides (o-CH3Bnimda, m-CH3Bnimda, p-CH3Bnimda, o-ClBnimda, m-ClBnimda, p-ClBnimda, p-FBnimda, and p-BrBnimda; o-CH3Bn = ortho-methylbenzyl, m-CH3Bn = meta-methylbenzyl, p-CH3Bn = para-methylbenzyl, o-ClBn = ortho-chlorobenzyl, m-ClBn = meta-chlorobenzyl, p-ClBn = para-chlorobenzyl, p-FBn = para-fluorobenzyl, and p-BrBn = para-bromobenzyl) with copper(ii) and nickel(ii) nitrate in aqueous solutions were investigated. Sixteen new complexes [Cu(o-CH3Bnimda)2](NO3)20.5H2O (1), [Cu(m-CH3Bnimda)2](NO3)2 (2), [Cu(p-CH3Bnimda)2](NO3)22H2O (3), [Cu(o-ClBnimda)2](NO3)2H2O (4), [Cu(m-ClBnimda)2](NO3)2 (5), [Cu(p-ClBnimda)2](NO3)22H2O (6), [Cu(p-FBnimda)2](NO3)22H2O (7), [Cu(p-BrBnimda)2](NO3)22H2O (8), [Ni(o-CH3Bnimda)2](NO3)2H2O (9), [Ni(m-CH3Bnimda)2](NO3)22H2O (10), [Ni(p-CH3Bnimda)2](NO3)2H2O (11), [Ni(o-ClBnimda)2](NO3)2 (12), [Ni(m-ClBnimda)2](NO3)22DMF (13) (DMF = N,N-dimethylformamide), [Ni(p-ClBnimda)2](NO3)22H2O (14), [Ni(p-FBnimda)2](NO3)2H2O (15), and [Ni(p-BrBnimda)2](NO3)22H2O (16) were prepared and characterized by infrared spectroscopy and thermal analysis (thermogravimetric and differential thermal analyses). The molecular and crystal structures of three complexes (2, 5, and 13) were determined by X-ray crystal structure analysis. The octahedral coordination environments around the copper(ii) and nickel(ii) ions in complexes 2, 5, and 13 consist of two O,N,O'-tridentate iminodiacetamide ligands. The complexes are trans-isomers with fac-configuration of the chelators.


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