Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Synthesis, Crystal Structure, and Photoluminescent Properties of a Series of LnIII–CuI Heterometallic Coordination Polymers Based on Cu4I3 Clusters and Ln–ina Rod Units

Chengcai Xia A , Gang Xiong A B , Lixin You A , Baoyi Ren A , Shuju Wang A and Yaguang Sun A B
+ Author Affiliations
- Author Affiliations

A Laboratory of Inorganic Molecule-Based Chemistry of Liaoning Province, and Laboratory of Coordination Chemistry, University of Chemical Technology, Shenyang 100142, China.

B Corresponding authors. Email: xg@syuct.edu.cn; sunyaguang@syuct.edu.cn

Australian Journal of Chemistry 70(8) 943-951 https://doi.org/10.1071/CH17076
Submitted: 7 February 2017  Accepted: 7 April 2017   Published: 5 May 2017

Abstract

A novel series of LnIII–CuI heterometallic coordination polymers (HCPs) {[Ln2Cu4I3(ina)7(DMA)2]n·nDMA, Ln = La (1), Ce (2), Pr (3) Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Dy (9) Ho (10), Er (11), Yb (12), Hina = isonicotinic acid, DMA = N,N-dimethylacetamide} were synthesised by a solvothermal reaction. The structures of compounds 112 were characterised by elemental analysis, FT-IR spectroscopy, thermogravimetric analysis, and powder X-ray diffraction. Single crystal X-ray diffraction studies revealed that 112 are isomorphous and are 3D heterometallic coordination polymers based on inorganic Cu4I3 clusters and Ln2(ina)7(DMA) rod units. In addition, the luminescent properties of compounds 59 have been investigated in detail. All of them exhibited green light emission due to the synergistic effects of characteristic emissions of lanthanide ions and iodide-to-copper charge transfer.


References

[1]  D. Lee, D. J. Williams, S. C. Vogel, T. Proffen, J. D. Thompson, L. L. Daemen, S. Park, Curr. Appl. Phys. 2016, 16, 1100.
         | CrossRef | open url image1

[2]  N. Domingo, E. Bellido, D. Ruiz-Molina, Chem. Soc. Rev. 2012, 41, 258.
         | CrossRef | 1:CAS:528:DC%2BC3MXhsFKntrfN&md5=8f85cb44f5f4bc755999af8f08e03544CAS | open url image1

[3]  K. Ariga, H. Ito, J. P. Hill, H. Tsukube, Chem. Soc. Rev. 2012, 41, 5800.
         | CrossRef | 1:CAS:528:DC%2BC38XhtFKjurzM&md5=8bc335678cd49895a0551c4b4cda944bCAS | open url image1

[4]  Y. N. Sun, G. Xiong, V. Dragutan, I. Dragutan, F. Ding, Y.-G. Sun, Inorg. Chem. Commun. 2015, 62, 103.
         | CrossRef | 1:CAS:528:DC%2BC2MXhslyqtrrM&md5=b22aea35236a4118500d211b2d9068bbCAS | open url image1

[5]  A. Granja, J. A. Alonso, I. Cabria, M. J. López, RSC Adv. 2015, 5, 47945.
         | CrossRef | 1:CAS:528:DC%2BC2MXnvF2qtrk%3D&md5=fb6fb3477f73bc84761588025016e450CAS | open url image1

[6]  M. Valenti, M. P. Jonsson, G. Biskos, A. Schmidt-Ott, W. A. Smith, J. Mater. Chem. A 2016, 4, 17891.
         | CrossRef | 1:CAS:528:DC%2BC28Xhs1amu7zJ&md5=43cde094f85697d639381d9a2227b764CAS | open url image1

[7]  (a) R. Sato, K. Suzuki, T. Minato, K. Yamaguchi, N. Mizuno, Inorg. Chem. 2016, 55, 2023.
         | CrossRef | 1:CAS:528:DC%2BC28XjtVOls7c%3D&md5=461fb9f69a278f89ffa46345b9bf5a4aCAS | open url image1
      (b) J. B. Peng, Q. C. Zhang, X. J. Kong, Y. Z. Zheng, Y. P. Ren, L. S. Long, R. B. Huang, L. S. Zheng, Z. P. Zheng, J. Am. Chem. Soc. 2012, 134, 3314.
         | CrossRef | open url image1

[8]  C. J. Chen, N. Wang, Y. Long, J. Y. Gao, W. P. Xie, X. R. Ran, S. T. Yue, CrystEngComm 2013, 15, 4611.
         | CrossRef | 1:CAS:528:DC%2BC3sXnvV2gtbs%3D&md5=6ea3e42bc763b73fac8a3b8cfc654c6bCAS | open url image1

[9]  R. T. Dong, X. L. Chen, X. Cui, S.-S. Chen, M. Y. Shen, C. W. Li, Q. H. Li, M.-Y. Hu, L.-F. Huang, H. Deng, CrystEngComm 2016, 18, 5547.
         | CrossRef | 1:CAS:528:DC%2BC28XpsVOmu7o%3D&md5=2b689cf17cd4de0dd90d228e80cd90e2CAS | open url image1

[10]  Y. G. Sun, G. Xiong, M. Y. Guo, F. Ding, S. J. Wang, P. F. Smet, D. Poelman, E. J. Gao, F. Verpoort, Dalton Trans. 2012, 41, 7670.
         | CrossRef | 1:CAS:528:DC%2BC38XotFGls74%3D&md5=35e604e5aef4cbe45a27293e69606b91CAS | open url image1

[11]  F. Farinella, L. Maini, P. P. Mazzeo, V. Fattori, F. Monti, D. Bragaa, Dalton Trans. 2016, 45, 17939.
         | CrossRef | 1:CAS:528:DC%2BC28Xhs1eks77L&md5=0f593b04c65993737d5b2632278961a0CAS | open url image1

[12]  Y. Kang, W.-H. Fang, L. Zhang, J. Zhang, Chem. Commun. 2015, 51, 8994.
         | CrossRef | 1:CAS:528:DC%2BC2MXmvFansLk%3D&md5=9e572a86e539c0373e6e5ac403f69808CAS | open url image1

[13]  B. J. Xin, G. Zeng, L. Gao, Y. Li, S. H. Xing, J. Hua, G. H. Li, Z. Shi, S. H. Feng, Dalton Trans. 2013, 42, 7562.
         | CrossRef | 1:CAS:528:DC%2BC3sXnsFaqsLg%3D&md5=3dad09654cc9164c5672b7f2797b510eCAS | open url image1

[14]  C.-W. Zhao, J.-P. Ma, Q.-K. Liu, X.-R. Wang, Y. Liu, J. Yang, J.-S. Yang, Y.-B. Dong, Chem. Commun. 2016, 52, 5238.
         | CrossRef | 1:CAS:528:DC%2BC28XivVKnsLk%3D&md5=2641ba52cbf935c15e8024dd9889ae2eCAS | open url image1

[15]  S. W. Zhang, P. Cheng, CrystEngComm 2015, 17, 4250.
         | CrossRef | 1:CAS:528:DC%2BC2MXmsFeltrw%3D&md5=70174775fe7f79f6375d8f69dffd5268CAS | open url image1

[16]  A. Yadav, A. Kumar Srivastava, A. Balamurugan, R. Boomishankar, Dalton Trans. 2014, 43, 8166.
         | CrossRef | 1:CAS:528:DC%2BC2cXotFWhurg%3D&md5=d031efd51e6d81278f634b96639df6f1CAS | open url image1

[17]  X. J. Yang, H. X. Li, Z. L. Xu, H.-Y. Li, Z.-G. Ren, J. P. Lang, CrystEngComm 2012, 14, 1641.
         | CrossRef | 1:CAS:528:DC%2BC38XhvVGjtbk%3D&md5=6ded66e01d2a25afe89042048b4f0d7dCAS | open url image1

[18]  W. H. Fang, G. Y. Yang, CrystEngComm 2013, 15, 9504.
         | CrossRef | 1:CAS:528:DC%2BC3sXhs12mu73M&md5=18cb9c4888bd948ba519eb88813027a5CAS | open url image1

[19]  R. H. Zeng, G. Peng, Y. C. Qiu, S. R. Zheng, W. S. Li, W. X. Zhang, H. Deng, Y. P. Cai, CrystEngComm 2011, 13, 3910.
         | CrossRef | 1:CAS:528:DC%2BC3MXmslajtrg%3D&md5=cddfb288d2e05c1cc231917d4f530c6aCAS | open url image1

[20]  O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Cryst. 2009, 42, 339.
         | CrossRef | 1:CAS:528:DC%2BD1MXjsFSnsbg%3D&md5=152b232aadeaa73225d2029119611dc4CAS | open url image1

[21]  (a) L. Palatinus, G. Chapuis, J. Appl. Cryst. 2007, 40, 786.
         | CrossRef | 1:CAS:528:DC%2BD2sXnslWqtrg%3D&md5=371d5f904cb15eff24165a8fb7fdba04CAS | open url image1
      (b) L. Palatinus, A. Van der Lee, J. Appl. Cryst. 2008, 41, 975.
         | CrossRef | open url image1
      (c) L. Palatinus, S. J. Prathapa, S. Van Smaalen, J. Appl. Cryst. 2012, 45, 575.
         | CrossRef | open url image1

[22]  G. M. Sheldrick, Acta Crystallogr. Sect. A 2008, 64, 112.
         | CrossRef | 1:CAS:528:DC%2BD2sXhsVGhurzO&md5=933d4ded754510f3d6dd59e45c48aab3CAS | open url image1

[23]  E. E. Delbridge, D. T. Dugah, C. R. Nelson, B. W. Skelton, A. H. White, Dalton Trans. 2007, 143.
         | CrossRef | 1:CAS:528:DC%2BD28XhtlemtbzE&md5=cdc2baa7b1e80ad67132e8cb8b54adc6CAS | open url image1

[24]  S. Sculfort, P. Braunstein, Chem. Soc. Rev. 2011, 40, 2741.
         | CrossRef | 1:CAS:528:DC%2BC3MXkvVWjtbs%3D&md5=c48817f7e3feb692ae1ad2c4e67bbdd6CAS | open url image1

[25]  (a) R. A. de Jesus, L. L. da Luz, D. O. Santos, J. A. Costa, S. Navickiene, C. C. Gatto, S. A. Junior, M. E. de Mesquita, Dalton Trans. 2015, 44, 17318.
         | CrossRef | 1:CAS:528:DC%2BC2MXhsVaqsbjO&md5=b0c8f5e15be756c5ac07c6ba13c1da5cCAS | open url image1
      (b) P. Falcaro, S. Furukawa, Angew. Chem. Int. Ed. 2012, 51, 8431.
         | CrossRef | open url image1
      (c) Y. L. Gai, K. C. Xiong, L. Chen, Y. Bu, X. J. Li, F. L. Jiang, M. C. Hong, Inorg. Chem. 2012, 51, 13128.
         | CrossRef | open url image1

[26]  J. P. Safko, J. E. Kuperstock, S. M. McCullough, A. M. Noviello, X. Li, J. P. Killarney, C. Murphy, H. H. Patterson, C. A. Bayse, R. D. Pike, Dalton Trans. 2012, 41, 11663.
         | CrossRef | 1:CAS:528:DC%2BC38XhtlamsLvM&md5=faabbb25affaf4dea894ab3f5d75f419CAS | open url image1

[27]  M. Guzik, E. Tomaszewicz, Y. Guyot, J. Legendziewicz, G. Boulon, J. Mater. Chem. C 2015, 3, 8582.
         | CrossRef | 1:CAS:528:DC%2BC2MXhtFKitrbI&md5=9b7a70377e9a08576e3d1a773ddc475eCAS | open url image1

[28]  (a) W. I. O’Malley, E. H. Abdelkader, M. L. Aulsebrook, R. Rubbiani, C. T. Loh, M. R. Grace, L. Spiccia, G. Gasser, G. Otting, K. L. Tuck, B. Graham, Inorg. Chem. 2016, 55, 1674.
         | CrossRef | 1:CAS:528:DC%2BC28XitVyns7c%3D&md5=d1f27e144d97c8fc6d3a3a124b2aa7f8CAS | open url image1
      (b) P. A. Smith, C. Crawford, N. Beedoe, Z. Assefa, R. E. Sykora, Inorg. Chem. 2012, 51, 12230.
         | CrossRef | open url image1
      (c) W. Wang, J. Yang, R. M. Wang, L. L. Zhang, J. F. Yu, D. F. Sun, Cryst. Growth Des. 2015, 15, 2589.
         | CrossRef | open url image1

[29]  S. Biju, M. L. P. Reddy, A. H. Cowley, K. V. Vasudevan, Cryst. Growth Des. 2009, 9, 3562.
         | CrossRef | 1:CAS:528:DC%2BD1MXmtl2msbw%3D&md5=d18a4a9c2ee0bedf0703f6fe09d8339bCAS | open url image1

[30]  (a) K. G. Sharma, N. R. Singh, New J. Chem. 2013, 37, 2784.
         | CrossRef | open url image1
      (b) J. P. Costes, S. Titos-Padilla, I. Oyarzabal, T. Gupta, C. Duhayon, G. Rajaraman, E. Colacio, Inorg. Chem. 2016, 55, 4428.
         | CrossRef | open url image1

[31]  X. C. Shan, F. L. Jiang, D. Q. Yuan, H. B. Zhang, M. Y. Wu, L. Chen, J. Wei, S. Q. Zhang, J. Pan, M. C. Hong, Chem. Sci. 2013, 4, 1484.
         | CrossRef | 1:CAS:528:DC%2BC3sXjtlynu7k%3D&md5=b9e8ecd674df3796077621f2424a16feCAS | open url image1



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