Some studies in inorganic complexes. I. Thallium(III)

Abstract

Investigations have been made into the structures of some thallium(III) complexes of 2,2'-dipyridyl, 1,10-phenanthroline, and ethylenediamine. From the substances investigated, the results indicate that where there are one or two molecules of ligand to one of thallic halide the complexes are uni-univalent electrolytes of the type [TlX₂B₂][TIX4] or [TlX₂B₂]X respectively, in which B is chelating base and X is halide ion.