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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Carbonyl halides of the Group VIII transition metals. II. Aquo adducts of Halobis(triphenylphosphine)dicarbonyls of cobalt(I)

JA Bowden and R Colton

Australian Journal of Chemistry 21(4) 891 - 895
Published: 1968

Abstract

Aquo adducts of halobis(triphenylphosphine)dicarbonylcobalt(1), Co(CO)2- (PPh3)2(H2O)X (X = Cl, Br, I), have been prepared by direct halogenation of the cation CO(CO)3(PPh3)2+, followed by addition of water. All of the compounds are stable in the solid state but they appear to undergo exchange reactions in solution.

https://doi.org/10.1071/CH9680891

© CSIRO 1968

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