The acid-catalysed rearrangement of (8R, l3R)-8,17-epoxylabd-14-en-13-ol; X-ray structure analysis of a tetracyclic ether product
JW Blunt, EJ Ditzel, MP Hartshorn, BJ Hickey, PK Johnstone, MHG Munro and WT Robinson
Australian Journal of Chemistry
34(11) 2475 - 2479
Published: 1981
Abstract
The structure and stereochemistry of the tetracyclic ether (5) formed in the acid-catalysed rearrangement of (8R,13R)-8,17-epoxylabd-14-en-13-ol (3) is presented. Although vinyl group participation was involved it was by a non-biosynthetic route.
https://doi.org/10.1071/CH9812475
© CSIRO 1981
