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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Reaction of 3-Oxoolean-12-en-29-oic Acid with Acetic Anhydride-Perchloric Acid

KL Gaul, KG Lewis, BW Skelton and AH White

Australian Journal of Chemistry 38(9) 1371 - 1380
Published: 1985

Abstract

Reaction of acetic anhydride- perchloric acid with 3-oxoolean-12-en-29- oic acid (4) gave either the enol acetate (6) or the derived γ- pyrono compound (8). The structure assigned to the latter was confirmed by a single-crystal X-ray structure determination. Comment is made on doubts about this reaction as a method of structure assignment.

https://doi.org/10.1071/CH9851371

© CSIRO 1985

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