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Environmental problems - Chemical approaches
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Environmental Chemistry

Environmental Chemistry

Volume 10 Number 1 2013

EN12159Evolving research directions in Surface Ocean–Lower Atmosphere (SOLAS) science

Cliff S. Law, Emilie Brévière, Gerrit de Leeuw, Véronique Garçon, Cécile Guieu, David J. Kieber, Stefan Kontradowitz, Aurélien Paulmier, Patricia K. Quinn, Eric S. Saltzman, Jacqueline Stefels and Roland von Glasow
pp. 1-16

Environmental context. Understanding the exchange of energy, gases and particles at the ocean–atmosphere interface is critical for the development of robust predictions of, and response to, future climate change. The international Surface Ocean–Lower Atmosphere Study (SOLAS) coordinates multi-disciplinary ocean–atmosphere research projects that quantify and characterise this exchange. This article details five new SOLAS research strategies – upwellings and associated oxygen minimum zones, sea ice, marine aerosols, atmospheric nutrient supply and ship emissions – that aim to improve knowledge in these critical areas.

EN12110Transformation of diphenylarsinic acid and related compounds in groundwater: production of thiol-containing arsenicals

Kunichika Nakamiya, Mitsuha Yoshikane, Hosoya Tomoko and Yasuyuki Shibata
pp. 17-21

Environmental context. Contamination of groundwater by arsenic compounds used in chemical warfare research is a recently discovered environmental problem in Japan. We report evidence that the arsenic compounds originally present in the groundwater are transforming to thio-arsenic compounds of currently unknown environmental fate.

EN12164In search of potential source regions of semi-volatile organic contaminants in air in the Yukon Territory, Canada from 2007 to 2009 using hybrid receptor models

John N. Westgate, Uwayemi M. Sofowote, Pat Roach, Phil Fellin, Ivy D'Sa, Ed Sverko, Yushan Su, Hayley Hung and Frank Wania
pp. 22-33

Environmental context. Some long-lived organic contaminants, such as chlorinated organics, brominated flame retardants and polycyclic aromatic hydrocarbons, can undergo transport through the atmosphere to remote regions. A series of measurements of these compounds taken over almost 3 years in the air at a remote location was combined with meteorological data to try to reveal potential source areas. After adjusting several parameters to optimise the method’s ability to identify sources it was found that for most contaminants no definitive sources are revealed.

EN12106The role of charge on the diffusion of solutes and nanoparticles (silicon nanocrystals, nTiO2, nAu) in a biofilm

Mahmood Golmohamadi, Rhett J. Clark, Jonathan G. C. Veinot and Kevin J. Wilkinson
pp. 34-41

Environmental context. The mobility and bioavailability of both contaminants and nutrients in the environment depends, to a large extent, on their diffusion. Because the majority of microorganisms in the environment are embedded in biofilms, it is essential to quantify diffusion in biofilms in order to evaluate the risk of emerging contaminants, including nanomaterials and charged solutes. This study quantifies diffusion, in a model environmental biofilm, for a number of model contaminants of variable size and charge.


Environmental context. We report the baseline levels of dissolved nutrients, organic matter and metals in the main temperate rivers draining the three Northern Galicia rias. Because the rivers are pristine, these rias are little affected by anthropogenic inputs, and their properties reflect the lithological characteristics of the rivers’ watersheds. Useful information in the development of European and global initiatives for assessing anthropogenic inputs to estuarine, coastal and open-sea environments has been provided.

EN12149Sources of ultrafine particles and chemical species along a traffic corridor: comparison of the results from two receptor models

Adrian J. Friend, Godwin A. Ayoko, Daniel Jager, Megan Wust, E. Rohan Jayaratne, Milan Jamriska and Lidia Morawska
pp. 54-63

Environmental context. Identifying the sources responsible for air pollution is crucial for reducing the effect of the pollutants on human health. The sources of the pollutants were found here by applying two mathematical models to data consisting of particle size distribution and chemical composition data. The identified sources could be used as the basis for controlling or reducing emissions of air pollution into the atmosphere.


Environmental context. Nitrogen is an essential nutrient for marine organisms, and thus an understanding of the marine nitrogen cycle is a crucial factor in predicting the sensitivity of marine life to environmental change. Hydroxylamine is a short-lived intermediate in nitrogen transformation processes, and reliable detection of this compound in seawater can help to identify these processes within the marine nitrogen cycle.

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