Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
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Investigation into the Initialization Behaviour of RAFT-Mediated Styrene–Maleic Anhydride Copolymerizations

Eric T. A. van den Dungen A , Jacques Rinquest A , Nadine O. Pretorius A , Jean M. McKenzie B , James B. McLeary A , Ron D. Sanderson A and Bert Klumperman A C D
+ Author Affiliations
- Author Affiliations

A UNESCO Centre for Macromolecules and Materials, Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland 7602, South Africa.

B Central Analytical Facility, University of Stellenbosch, Matieland 7602, South Africa.

C Laboratory of Polymer Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands.

D Corresponding author. Email: l.klumperman@tue.nl

Australian Journal of Chemistry 59(10) 742-748 https://doi.org/10.1071/CH06238
Submitted: 7 July 2006  Accepted: 14 September 2006   Published: 30 October 2006

Abstract

The living radical alternating copolymerization of styrene and maleic anhydride mediated by the reversible addition–fragmentation chain transfer (RAFT) polymerization process has been studied at short chain lengths using two different dithiobenzoate RAFT agents. The results indicate specificity of addition of the RAFT-agent leaving groups for either styrene or maleic anhydride. The addition rate of the monomers and the fact that monomers are added individually favour the penultimate unit model of polymer propagation.


Acknowledgments

We thank the NMR laboratories of the University of Stellenbosch for the generous instrument time, the Dutch Polymer Institute for the financial support of the project, and the National Research Foundation of South Africa.


References


[1]   G. Moad, E. Rizzardo, D. H. Solomon, Macromolecules 1982, 15,  909.
        | CrossRef |   open url image1

[2]   J.-S. Wang, K. Matyjaszewski, J. Am. Chem. Soc. 1995, 117,  5614.
        | CrossRef |   open url image1

[3]   T. P. Le, G. Moad, E. Rizzardo, S. H. Thang, PCT Int. Appl. WO98/01478 1998.

[4]   J. Chiefari, Y. K. B. Chong, F. Ercole, J. Krstina, J. Jeffery, T. P. T. Le, R. T. A. Mayadunne, G. F. Meijs, C. L. Moad, G. Moad, E. Rizzardo, S. H. Thang, Macromolecules 1998, 31,  5559.
        | CrossRef |   open url image1

[5]   G. Moad, E. Rizzardo, S. H. Thang, Aust. J. Chem. 2005, 58,  379.
        | CrossRef |   open url image1

[6]   C. Barner-Kowollik, M. Buback, B. Charleux, M. L. Coote, M. Drache, T. Fukuda, A. Goto, B. Klumperman, A. B. Lowe, J. B. McLeary, G. Moad, M. J. Monteiro, R. D. Sanderson, M. P. Tonge, P. Vana, J. Polym. Sci., Part A: Polym. Chem. 2006, 44,  5809.
        | CrossRef |   open url image1

[7]   D. Benoit, C. J. Hawker, E. E. Huang, Z. Lin, T. P. Russell, Macromolecules 2000, 33,  1505.
        | CrossRef |   open url image1

[8]   H. de Brouwer, M. A. J. Schellekens, B. Klumperman, M. J. Monteiro, A. L. German, J. Polym. Sci., Part A: Polym. Chem. 2000, 38,  3596.
        | CrossRef |   open url image1

[9]   Y.-Z. You, C.-Y. Hong, C.-Y. Pan, Eur. Polym. J. 2002, 38,  1289.
        | CrossRef |   open url image1

[10]   E. Chernikova, P. Terpugova, C. Bui, B. Charleux, Polymer 2003, 44,  4101.
        | CrossRef |   open url image1

[11]   M. C. Davies, J. V. Dawkins, D. J. Hourston, Polymer 2005, 46,  1739.
        | CrossRef |   open url image1

[12]   F.-S. Du, M.-Q. Zhu, H.-Q. Guo, Z.-C. Li, F.-M. Li, M. Kamachi, A. Kajiwara, Macromolecules 2002, 35,  6739.
        | CrossRef |   open url image1

[13]   J. Brandrup, E. H. Immergut, E. A. Grulke, Polymer Handbook 1999 (John Wiley: New York, NY).

[14]   E.-S. Park, M.-N. Kim, I.-M. Lee, H. S. Lee, J.-S. Yoon, J. Polym. Sci., Part A: Polym. Chem. 2000, 38,  2239.
        | CrossRef |   open url image1

[15]   M.-Q. Zhu, L.-H. Wei, M. Li, L. Jiang, F.-S. Du, Z.-C. Li, F.-M. Li, Chem. Commun. 2001,  365.
        | CrossRef |   open url image1

[16]   S. Harrisson, K. L. Wooley, Chem. Commun. 2005,  3259.
        | CrossRef |   open url image1

[17]   R. A. Sanayei, K. F. O'Driscoll, B. Klumperman, Macromolecules 1994, 27,  5577.
        | CrossRef |   open url image1

[18]   H. K. Hall, A. Buyle Padias, J. Polym. Sci., Part A: Polym. Chem. 2001, 39,  2069.
        | CrossRef |   open url image1

[19]   D. J. T. Hill, J. H. O'Donnell, P. W. O'Sullivan, Macromolecules 1985, 18,  9.
        | CrossRef |   open url image1

[20]   N.-T. H. Ha, K. Fujimori, Acta Polym. 1998, 49,  404.
        | CrossRef |   open url image1

[21]   A. L. Van Geet, Anal. Chem. 1968, 40,  2227.
        | CrossRef |   open url image1

[22]   J. B. McLeary, F. M. Calitz, J. M. McKenzie, M. P. Tonge, R. D. Sanderson, B. Klumperman, Macromolecules 2004, 37,  2383.
        | CrossRef |   open url image1

[23]   J. B. McLeary, F. M. Calitz, J. M. McKenzie, M. P. Tonge, R. D. Sanderson, B. Klumperman, Macromolecules 2005, 38,  3151.
        | CrossRef |   open url image1

[24]   J. B. McLeary, J. McKenzie, M. Tonge, R. Sanderson, B. Klumperman, Chem. Commun 2004,  1950.
        | CrossRef |   open url image1

[25]   B. Klumperman, G. Vonk, Eur. Polym. J. 1994, 30,  955.
        | CrossRef |   open url image1

[26]   B. Klumperman, J. B. McLeary, E. T. A. van den Dungen, W.-J. Soer, J. S. Bozovic, in Progress in Controlled/Living Radical Polymerization, ACS Symp. Ser. 944 (Ed. K. Matyjaszewski) 2006, p. 501 (ACS: Washington, DC).



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