Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
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Formation of Ternary Complexes of Iron(iii) Cations in Solution and Gas Phase

Xing Xin Liu A and Artem Melman A B
+ Author Affiliations
- Author Affiliations

A Department of Chemistry and Biomolecular Science, Clarkson University, Potsdam, NY 13676, USA.

B Corresponding author. Email: amelman@clarkson.edu

Australian Journal of Chemistry 66(7) 791-797 https://doi.org/10.1071/CH13179
Submitted: 15 April 2013  Accepted: 24 May 2013   Published: 11 June 2013

Abstract

Formation of labile 1 : 1 : 1 ternary mononuclear complexes of iron(iii) cation with η3-terdentate meridional binders was studied using electrospray ionisation mass spectrometry (ESI-MS) titration and UV-Vis titration in solution phase. Low selectivities towards formation of ternary heteroleptic complexes in the solution phase vs. symmetric 2 : 1 complexes were obtained with combinations of dianionic 2,6-bis[hydroxy(methyl)amino]-1,3,5-triazine (BHT) ligands with monoanionic terdentate ligands such as 2-[(2-pyridinylmethylene)amino]phenol. Moderate selectivities were observed in formation of ternary iron(iii) complexes of iron(iii) between BHT ligands and neutral terdentate ligands such as pyridin-2-ylmethylpyridin-2-ylmethyleneamine. Results obtained by MS titrations were in a reasonable agreement with UV titration data indicating that quantitative ESI MS spectrometry can be applied to these labile iron(iii) complexes.


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