Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Crystallisation-Driven Self-Sorting of H-Bonded Guanidinium or Sodium Sulfonate Constitutional Molecular Frameworks

Dan Dumitrescu A , Yves-Marie Legrand A , Nathalie Masquelez A , Arie van der Lee A and Mihail Barboiu A B
+ Author Affiliations
- Author Affiliations

A Institut Européen des Membranes – ENSCM-UMII-CNRS 5635, Place Eugène Bataillon, CC 047, F-34095 Montpellier, Cedex 5, France.

B Corresponding author. Email: mihail-dumitru.barboiu@univ-montp2.fr

Australian Journal of Chemistry 67(7) 1005-1010 https://doi.org/10.1071/CH14053
Submitted: 5 February 2014  Accepted: 4 March 2014   Published: 24 March 2014

Abstract

Four single crystal structures were obtained in order to better understand the difference between the crystallisation-driven formation of solid state organo-sulfonate guanidinium superstructures and their sodium salt analogues. 5-Formyl-2-furfuryl sulfonate and 4,4′-diamino-2,2′-biphenyl disulfonate were chosen as anions due to functional and geometrical considerations together with guanidinium, aminoguanidinium, and sodium cations. 5-Formyl-2-fufuryl sulfonate reacts with aminoguanidinium cation in water leading to an imino-zwitterionic compound, able to form on its own a guanidinium-sulfonate superstructure in crystalline state.


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