Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science

Topological Resonance Energies: a Caveat

RF Langler

Australian Journal of Chemistry 44(2) 297 - 302
Published: 1991


Even hydrocarbon Lewis structures which must have two non-bonding electrons are examined. Such structures are shown to have surprisingly large topological resonance energies. Three theorems are presented which permit the general conclusion that the propensity for topological resonance energies to lead to 'obviously false chemical conclusions' originates with the 'π-energies' produced from the matching polynomials for even hydrocarbons with non-bonding electrons.

© CSIRO 1991

Rent Article (via Deepdyve) Export Citation Cited By (3)