
TY  - JOUR
A1  - Curtis, Neil F. 
A1  - Gladhikh, Olga P. 
A1  - Morgan, Keith R. 
A1  - Heath, Sarah L. 
T1  - A Centrosymmetrical Di-thiolato-bridged Dinuclear Nickel(II) Compound; Bis-&#181;-<emph type="2">S</emph>-(7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolato)dinickel(II) Perchlorate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1998
VL  - 51
IS  - 1
SP  - 49
EP  - 54
KW  - 
UR  - https://doi.org/10.1071/C97005 
N2  - The title compound, formed by reaction of 4-mercapto-4-methylpentan-2-one with bis(ethane-1,2-diamine)nickel(II) perchlorate, has a centrosymmetrical dinuclear cation. Each singlet ground-state nickel(II) ion is in tetrahedrally twisted square-planar coordination by the primary amine and imine nitrogen atoms and the thiolato sulfur atom of one molecule of 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolate (adet&#175;), and the sulfur atom of another molecule, with the sulfur atoms of two ligands forming a planar Ni2S2 bridging group &#123;&#91;Ni2-&#181;-(adet)2&#93; (ClO4)2, C16H34C12N4Ni2O8S2, Mr 662&#183;9, monoclinic, P21/c, a 8&#183;267(1), b 9&#183;952(1), c 16&#183;234(2) &#197;, &#946; 103&#183;010(2)&#176;, R1 0&#183;033 for 2531 reflections&#125;. 
ER  -

