
%0 Journal Article
%A Goodwin, HA 
%A Smith, FE 
%A Konig, E 
%A Ritter, G 
%T METAL COMPLEXES OF 1,10-PHENANTHROLINE DERIVATIVES V.* BIS-LIGAND IRON(II) COMPLEXES OF 1 ,10-PHENANTHROLINE-2-CARBOTHIOAMIDE
%J Australian Journal of Chemistry
%D 1973/03/01
%V 26
%N 3
%P 521-528
%K 
%R https://doi.org/10.1071/CH9730521
%U https://www.publish.csiro.au/paper/CH9730521 
%X The preparation of 1,10-phenanthroline-2-carbothioamidea nd its bis-ligand complexes of iron(II) is described. The ligand produces a strong field and the magnetic and Mossbauer effect data for the complexes indicate that in these the metal atom has a 1A1 ground state. The ligand can coordinate as a neutral or anionic tridentate, producing either cationic or neutral complexes. The electronic spectra of the cationic complexes are typical for the iron(II)-bis-terimine system and show intense charge-transfer absorption. Infrared data indicate that the sulphur atom of the thioamido group is coordinated. 
