
%0 Journal Article
%A Dilli, S 
%A Patsalides, E 
%T A convenient new Method for the preparation of vanadium(III) &#946;-diketonates
%J Australian Journal of Chemistry
%D 1976/11/01
%V 29
%N 11
%P 2389-2393
%K 
%R https://doi.org/10.1071/CH9762389
%U https://www.publish.csiro.au/paper/CH9762389 
%X The vanadium(111) tris-&#946;-diketonates derived from pentane-2,4-dione and 13 other &#946;-diketones were prepared by reduction of oxovanadium(1V) sulphate with sodium dithionite and chelation of the vanadium(111) with ligand in an aqueous alcohol medium. The chelate prepared with pentane-2,4-dione was also obtained by reduction of ammonium vanadate and oxobis(pentane-2,4-dionato)-vanadium(1V). Preparative details are given and the advantages, and some difficulties, of the method are discussed. 
