
TY  - JOUR
A1  - Dilli, S 
A1  - Patsalides, E 
T1  - A convenient new Method for the preparation of vanadium(III) &#946;-diketonates
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 11
SP  - 2389
EP  - 2393
KW  - 
UR  - https://doi.org/10.1071/CH9762389 
N2  - The vanadium(111) tris-&#946;-diketonates derived from pentane-2,4-dione and 13 other &#946;-diketones were prepared by reduction of oxovanadium(1V) sulphate with sodium dithionite and chelation of the vanadium(111) with ligand in an aqueous alcohol medium. The chelate prepared with pentane-2,4-dione was also obtained by reduction of ammonium vanadate and oxobis(pentane-2,4-dionato)-vanadium(1V). Preparative details are given and the advantages, and some difficulties, of the method are discussed. 
ER  -

