
TY  - JOUR
A1  - Raston, CL 
A1  - White, AH 
A1  - Winter, G 
T1  - Crystal structure of Tetraethylammonium Tetrakis(O-ethylxanthato)bismuthate(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 10
SP  - 2207
EP  - 2212
KW  - 
UR  - https://doi.org/10.1071/CH9782207 
N2  - The crystal structure of the title compound (NEt4) [Bi(S2COEt)4] has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0.051 for 1560 'observed' reflections. Crystals are monoclinic, P21, a 10.947(2), b 16.334(4), c 10.589(2)&#506;, &#946; 116.04(2)&#176;, Z 2. The bismuth coordination stereochemistry is dodecahedral, Bi-S ranging from 2.803(11) to 2.972(10) &#506;; the three longest distances occupy a triangular face in the coordination polyhedron and may indicate the presence of a stereochemically active lone pair. 
ER  -

