
TY  - JOUR
A1  - Long, MA 
A1  - Garnett, JL 
A1  - Lukey, CA 
A1  - Williams, PG 
T1  - Metal-catalysed exchange of alkyl and silyl hydrogen in organosilanes with tritium gas over Raney nickel as measured by <sup>3</sup>H N.M.R
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 6
SP  - 1393
EP  - 1395
KW  - 
UR  - https://doi.org/10.1071/CH9801393 
N2  - Analysis by tritium n.m.r, of triethylsilane, tetramethylsilane, hexamethyldisiloxane and chlorodimethylsilane exchanged with tritium gas over Raney nickel at 100&#176;C shows that exchange readily occurs in alkyl substituents as well as with silyl hydrogen; novel species involving charge-transfer intermediates in dissociative adsorption at the C-H as well as the Si-H bonds are proposed to explain the data. 
ER  -

