In years of average to below average annual rainfall, throughflow was the most important transport pathway for contaminants. However, it was expected that overland flow will be the dominant transport pathway when annual rainfall is above about 550 mm. Changes in water content of the texture-contrast soils was caused by seasonal rainfall causing periodic saturation, by waterlogging, groundwater, or both. This affected the type and form of contaminant. For example, Na and Cl concentrations were generally only large (800 and 1500 mg/L, respectively) on the lower slopes but in the wettest seasons their concentrations increased at depth on mid-slopes due to the influence of shallow saline groundwater. These chemicals then leached when groundwater levels subsided. The results suggest that ameliorative strategies to reduce agricultural contaminants should target the transport pathways specific to each chemical species, at the point (or points) in the landscape where they are generated.