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Article << Previous     |     Next >>   Contents Vol 57(5)

The Role of Hydrogen Bonding in the Intramolecular Cyclization of Carbenes

David W. Jeffery, Troy Lister and Rolf H. Prager

Australian Journal of Chemistry 57(5) 491 - 496

Abstract

The cyclization products from the photolysis of 3-arylamino-4-ethoxycarbonyl-2-heteroarylisoxazol-5(2H)-ones are interpreted as arising from intramolecular cyclization of carbenes. The mode of cyclization appears to be controlled by hydrogen bonding of the 3-NH group with either the 2-heteroaryl group or the 4-ethoxycarbonyl group.



Full text doi:10.1071/CH03139

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