The 3-Hydroxycineoles

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Contents Vol 58(11)

doi:10.1071/CH05144

The 3-Hydroxycineoles

Raymond M. Carman ^A ^C, Ward T. Robinson ^B, Craig J. Wallis ^A

^A Chemistry, University of Queensland, Brisbane QLD 4072, Australia.
^B Department of Chemistry, University of Canterbury, Christchurch, New Zealand.
^C Corresponding author. Email: carman@chemistry.uq.edu.au





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Australian Journal of Chemistry 58(11) 785–791 http://dx.doi.org/10.1071/CH05144
Submitted: 20 June 2005 Accepted: 21 September 2005 Published online: 9 December 2005

Abstract

Data concerning the 3-hydroxycineoles 1 and 2 are provided to enable the ready identification of these metabolites and to determine their enantiomeric excess in mixtures. An unusual S_N2-type inversion at a tertiary center is observed during one synthetic approach.