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Construction of the 1,2,3,4-Tetrahydro-1,4,6,2-oxathiazaphosphorine Ring System
Wynona M.
Johnson A B,
Kathleen A.
Turner A
A
CSIRO Molecular and Health Technologies, Clayton South VIC 3169, Australia.
B
Corresponding author. Email: noni.johnson@csiro.au
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Australian Journal of Chemistry 58(12) 834–836 http://dx.doi.org/10.1071/CH05190
Submitted: 16 August 2005
Accepted: 21 October 2005
Published online: 20 December 2005
Abstract
The novel 1,2,3,4-tetrahydro-1,4,6,2-oxathiazaphosphorine ring system has been prepared by reaction of the sodium salt of diethyl mercaptomethylphosphonate with nitrile oxides, followed by cyclization of the resulting hydroximinoyl sulfide. The stability of the new ring system is investigated.
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