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[Ag(isonicotinamide)2NO3]2 – a Stable Form of Silver Nitrate
Thomas
Dorn A,
Katharina M.
Fromm B,
Christoph
Janiak A C
A
Institut für Anorganische und Analytische Chemie, Universität Freiburg, 79104 Freiburg, Germany.
B
Department of Chemistry, University of Basel, 4056 Basel, Switzerland.
C
Corresponding author. Email: janiak@uni-freiburg.de
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Australian Journal of Chemistry 59(1) 22–25 http://dx.doi.org/10.1071/CH05270
Submitted: 10 October 2005
Accepted: 14 November 2005
Published online: 31 January 2006
Abstract
[Ag(isonicotinamide)2NO3]2, featuring a short Ag···Ag contact and a strong hydrogen-bonding network in the solid state, is a light-stable and still readily soluble form of silver nitrate, showing little complex formation in solution but a counter-intuitive decrease in dissolution rate with decrease of pH.
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