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An Interpenetrating Coordination Polymer Containing Weak Hydrogen Bonds and Argentophilic Interactions
Martin B.
Duriska A,
Stuart R.
Batten A B,
David J.
Price A
A
School of Chemistry, Monash University, Melbourne VIC 3800, Australia.
B
Corresponding author. Email: stuart.batten@sci.monash.edu.au
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Australian Journal of Chemistry 59(1) 26–29 http://dx.doi.org/10.1071/CH05304
Submitted: 14 November 2005
Accepted: 15 December 2005
Published online: 31 January 2006
Abstract
The structure of the coordination polymer [Ni(en)2][Ag(CN)2]2[Ag2(CN)2] (1; en = ethylenediamine) contains 2D (6,3) sheets in which trans-Ni(en)2{Ag(CN)2}2 moieties bridge between zigzag Ag(CN) chains. The sheets are puckered, and show 3-fold 2D → 2D parallel interpenetration. The structure also contains weak N–H···π(CN) and argentophilic Ag···Ag interactions between the 2D sheets.
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