A Planar Silver(I) Complex with a 'Simple' 2,2?-Bipyridine Ligand

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Contents Vol 59(1)

doi:10.1071/CH06013

A Planar Silver(i) Complex with a ‘Simple’ 2,2′-Bipyridine Ligand

Edwin C. Constable ^A ^D, Catherine E. Housecroft ^A, Benson M. Kariuki ^B, Christopher B. Smith ^A ^C

^A Department of Chemistry, 4056 Basel, Switzerland.
^B School of Chemistry, University of Birmingham, Birmingham B15 2TT, UK.
^C Current address: School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia, Perth WA 6009, Australia.
^D Corresponding author. Email: edwin.constable@unibas.ch





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Australian Journal of Chemistry 59(1) 30–33 http://dx.doi.org/10.1071/CH06013
Submitted: 6 January 2006 Accepted: 11 January 2006 Published online: 31 January 2006

Abstract

The phenol-functionalized 2,2′-bipyridine ligand 1 forms a silver(i) complex containing [Ag(1)₂]⁺ cations that are best described as having a planar coordination environment.