Functionalization of Baylis–Hillman Bromides with Symmetric and Asymmetric Bifunctional Aromatics

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Contents Vol 60(3)

doi:10.1071/CH06342

Functionalization of Baylis–Hillman Bromides with Symmetric and Asymmetric Bifunctional Aromatics

Yusuf Zulykama ^A, Paramasivan T. Perumal ^A ^B

^A Organic Chemistry Division, Central Leather Research Institute, Adyar, Chennai-20, India.
^B Corresponding author. Email: ptperumal@gmail.com





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Australian Journal of Chemistry 60(3) 205–210 http://dx.doi.org/10.1071/CH06342
Submitted: 19 September 2006 Accepted: 23 February 2007 Published online: 2 April 2007

Abstract

Nucleophilic substitution products of Baylis–Hillman adducts are valuable synthons. In an attempt to improve the functionality of Baylis–Hillman adducts we report the regio- and chemo-selective fuctionalization of Baylis–Hillman bromides with symmetric and asymmetric bifunctional aromatics.