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Article << Previous     |     Next >>   Contents Vol 61(1)

A Hückel-Level Kinetic-Stability-Based Approach to Aromaticity: Cyclic Even Alternant Hydrocarbons

Richard F. Langler

Department of Chemistry, Mount Allison University, Sackville, New Brunswick, E4L 1G8, Canada. Email: rlangler@mta.ca
 
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Abstract

A graph-theoretical procedure is described that relates Hückel-level expectations for the kinetic stabilities of even, alternant hydrocarbons to their Lewis structures. New parameters Ac and T are developed. A universal kinetic-stability-based standard is proposed for classifying alternant hydrocarbons as aromatic, non-aromatic, or anti-aromatic.

   
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