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Granulated Carbon Nanotubes as the Catalyst Support for Pt for the Hydrogenation of Nitrobenzene
Shao
Jin A B,
Weizhong
Qian A C,
Yi
Liu A,
Fei
Wei A,
Dezeng
Wang A,
Jinchang
Zhang B
A
Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China.
B
Department of Applied Chemistry, School of Science, Beijing University of Chemical Technology, Beijing, 100029, China.
C
Corresponding author. Email: qianwz@tsinghua.edu.cn
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Australian Journal of Chemistry 63(1) 131–134 http://dx.doi.org/10.1071/CH09162
Submitted: 17 March 2009
Accepted: 17 August 2009
Published online: 8 January 2010
Abstract
Granulated Pt/carbon nanotubes (CNTs) were found to have a much better catalytic activity in the liquid phase hydrogenation of nitrobenzene than Pt/activated carbon (AC). The granulated CNTs had much larger pores than the AC particles, which gave a faster mass transfer rate of H2 that helped produce aniline with high selectivity.
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